Issue 62, 2018

Schiff-base coordination complexes with plutonium(iv) and cerium(iv)

Abstract

PuL2 and CeL2 (L = N,N′-bis[(4,4′-diethylamino)salicylidene]-1,2-phenylenediamine) have been synthesized, and characterized by single crystal X-ray diffraction, UV/vis/NIR spectroscopy, and cyclic voltammetry. These studies reveal the enhanced stabilization of Pu(IV) versus Ce(IV) with this Schiff base, and quasi-reversible redox behaviour only with the plutonium complex.

Graphical abstract: Schiff-base coordination complexes with plutonium(iv) and cerium(iv)

Supplementary files

Article information

Article type
Communication
Submitted
03 Mei 2018
Accepted
05 Jul 2018
First published
06 Jul 2018

Chem. Commun., 2018,54, 8634-8636

Author version available

Schiff-base coordination complexes with plutonium(IV) and cerium(IV)

B. E. Klamm, C. J. Windorff, M. L. Marsh, D. S. Meeker and T. E. Albrecht-Schmitt, Chem. Commun., 2018, 54, 8634 DOI: 10.1039/C8CC03571G

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