Flexible monomer-based covalent organic frameworks: design, structure and functions

Lanfang Zou; Xinyu Yang; Shuai Yuan; Hong-Cai Zhou

doi:10.1039/C7CE00593H

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Flexible monomer-based covalent organic frameworks: design, structure and functions†

Lanfang Zou,

‡^a Xinyu Yang,‡^a Shuai Yuan^a and Hong-Cai Zhou

*^ab

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* Corresponding authors

^a Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA
E-mail: zhou@chem.tamu.edu

^b Department of Materials Science and Engineering, Texas A&M University, College Station, TX 77843, USA

Abstract

The design and synthesis of flexible monomer-based covalent organic frameworks (COFs) have been considered a challenge. Herein, we describe the design and synthesis of a new flexible monomer-based COF, termed PPN-30 (PPN meaning porous polymer network), by the use of a flexible alkyl amine, 1,4-cyclohexanediamine, combined with 1,3,5-triformylbenzene. The structure and gas adsorption properties of PPN-30 were carefully investigated.

This article is part of the themed collection: Covalent organic frameworks and organic cage structures

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Article information

DOI: https://doi.org/10.1039/C7CE00593H
Article type: Communication
Submitted: 27 Mac 2017
Accepted: 12 Apr 2017
First published: 12 Apr 2017

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CrystEngComm, 2017,19, 4868-4871

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Flexible monomer-based covalent organic frameworks: design, structure and functions

L. Zou, X. Yang, S. Yuan and H. Zhou, CrystEngComm, 2017, 19, 4868 DOI: 10.1039/C7CE00593H

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CrystEngComm

Flexible monomer-based covalent organic frameworks: design, structure and functions†

Abstract

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Flexible monomer-based covalent organic frameworks: design, structure and functions

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