Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

Ming Luo; Congqing Zhu; Lina Chen; Hong Zhang; Haiping Xia

doi:10.1039/C5SC03963K

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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion†

Ming Luo,^a Congqing Zhu,^a Lina Chen,^a Hong Zhang*^a and Haiping Xia*^a

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* Corresponding authors

^a State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: zh@xmu.edu.cn, hpxia@xmu.edu.cn

Abstract

The halogenation of metallapentalyne led to the formation of metallapentalenes, which were fully characterized and studied by DFT calculations. The experimental and computational studies indicate that four resonance forms contribute to the overall structure of the metallapentalenes, and one resonance form could be viewed as the first examples of metallaiodirenium and metallabromirenium ions.

This article is part of the themed collection: Celebrating a Century of Excellency in Chemistry at Xiamen University

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DOI: https://doi.org/10.1039/C5SC03963K
Article type: Edge Article
Submitted: 20 Okt 2015
Accepted: 17 Nov 2015
First published: 23 Nov 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry

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Chem. Sci., 2016,7, 1815-1818

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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

M. Luo, C. Zhu, L. Chen, H. Zhang and H. Xia, Chem. Sci., 2016, 7, 1815 DOI: 10.1039/C5SC03963K

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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion†

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Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

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