Issue 3, 2016

Discoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(i) or copper(ii) template?

Abstract

We report here a DCL study of a phenanthroline-based building block focusing on catenane formation with copper templates. Two [2]catenanes have been amplified by using Cu+ as a template from the DCLs that contain no interlocked compounds in the absence of copper. In addition, an unexpected Cu2+ template effect on the [2]catenane formation was discovered. The observed Cu2+ template effect was found to originate from the in situ reduction of the divalent metal to Cu+.

Graphical abstract: Discoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(i) or copper(ii) template?

Supplementary files

Article information

Article type
Research Article
Submitted
30 Okt 2015
Accepted
07 Des 2015
First published
04 Jan 2016

Inorg. Chem. Front., 2016,3, 348-353

Author version available

Discoveries from a phenanthroline-based dynamic combinatorial library: catenane from a copper(I) or copper(II) template?

K. Tong, C. Yee, Y. C. Tse and H. Y. Au-Yeung, Inorg. Chem. Front., 2016, 3, 348 DOI: 10.1039/C5QI00227C

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