Issue 45, 2013

In situ growth of luminescent MOF thin films of Sr/Eu(ii)-imidazolate on functionalized nanostructured alumina

Abstract

The highly luminescent framework series 3[Sr1−xEuxIm2], x = 0–1, was successfully grown in situ on nanostructured macroporous anodic aluminium oxide (AAO) membranes during the framework formation. Thereby, a novel in situ coating strategy for thin film creation of metal–organic frameworks (MOFs) and dense frameworks directly deriving from the metals was developed. Depending on synthesis conditions and growth duration, the luminescent materials start growing inside the AAO macropores and on the pore mouths, yielding patterned framework surfaces, before a continuous smooth MOF layer is formed. The films retain the luminescence of the corresponding bulk materials and can be grown with variable film thickness on the nanometer scale.

Graphical abstract: In situ growth of luminescent MOF thin films of Sr/Eu(ii)-imidazolate on functionalized nanostructured alumina

Supplementary files

Article information

Article type
Communication
Submitted
10 Jun 2013
Accepted
29 Ago 2013
First published
29 Ago 2013

CrystEngComm, 2013,15, 9382-9386

In situ growth of luminescent MOF thin films of Sr/Eu(II)-imidazolate on functionalized nanostructured alumina

L. V. Meyer, J. Vogt, F. A. Brede, H. Schäfer, M. Steinhart and K. Müller-Buschbaum, CrystEngComm, 2013, 15, 9382 DOI: 10.1039/C3CE41087K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements