Issue 65, 2012
From the journal:

Chemical Communications

Palladium-catalysed heteroannulation of [60]fullerene with N-benzyl sulfonamides and subsequent functionalisation†‡§

Yi-Tan Su,a   You-Liang Wanga  and  Guan-Wu Wang*ab  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: gwang@ustc.edu.cn
Fax: +86 551 3607864
Tel: +86 551 3607864

b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, P. R. China

Abstract

The palladium-catalysed heteroannulation of [60]fullerene with various N-benzyl sulfonamides via C–H bond activation affords [60]fullerene-fused tetrahydroisoquinolines. In the presence of a Brønsted acid [60]fullerene-fused tetrahydroisoquinolines are transformed to [60]fullerene-fused indanes, in which the sulfonamide group can be removed or replaced with an aryl group.

Graphical abstract: Palladium-catalysed heteroannulation of [60]fullerene with N-benzyl sulfonamides and subsequent functionalisation

  • This article is part of the themed collection: Aromaticity
About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC33923D
Article type
Communication
Submitted
31 Mei 2012
Accepted
22 Jun 2012
First published
09 Jul 2012

Chem. Commun., 2012,48, 8132-8134

Permissions

Request permissions

Palladium-catalysed heteroannulation of [60]fullerene with N-benzyl sulfonamides and subsequent functionalisation

Y. Su, Y. Wang and G. Wang, Chem. Commun., 2012, 48, 8132 DOI: 10.1039/C2CC33923D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements