Issue 6, 2010
From the journal:

Chemical Communications

Gold(i)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes†‡

Youssef Harrak,a   Antoine Simonneau,a   Max Malacria,*a   Vincent Gandon*b  and  Louis Fensterbank*a  

* Corresponding authors

a UPMC Univ Paris 06, UMR CNRS 7201, 4 place Jussieu, 75005 Paris, France
E-mail: louis.fensterbank@upmc.fr

b Univ Paris-Sud, UMR CNRS 8182, Orsay 91405, France
E-mail: vincent.gandon@icmo.u-psud.fr

Abstract

1,6-Enynes can be transformed into vinylidenecyclopentanes via gold-promoted 5-exo dig cyclisation followed by 1,5-hydride or -alkoxide shift.

Graphical abstract: Gold(i)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

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Article information

DOI
https://doi.org/10.1039/B919240A
Article type
Communication
Submitted
16 Sep 2009
Accepted
17 Des 2009
First published
07 Jan 2010

Chem. Commun., 2010,46, 865-867

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Gold(I)-catalysed cycloisomerisation of 1,6-enynes into functionalised allenes

Y. Harrak, A. Simonneau, M. Malacria, V. Gandon and L. Fensterbank, Chem. Commun., 2010, 46, 865 DOI: 10.1039/B919240A

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