Issue 6, 2007
From the journal:

CrystEngComm

The first example of a coordination polymer from the expanded 4,4′-bipyridineligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

Jonathon E. Beves,a   Edwin C. Constable,*a   Catherine E. Housecroft,a   Cameron J. Kepertb  and  David J. Priceb  

* Corresponding authors

a Department of Chemistry, University of Basel, Spitalstrasse 51, Basel, Switzerland
E-mail: edwin.constable@unibas.ch
Fax: +41 61 267 1005
Tel: +41 61 267 100

b School of Chemistry, University of Sydney, NSW, Australia
E-mail: c.kepert@chem.usyd.edu.au

Abstract

The complex cation ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine) is an expanded 4,4′-bipyridine; we describe the first example of a coordination polymer in which [Ru(pytpy)2]2+ plays the role of a bridging bidentate ligand.

Graphical abstract: The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

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Article information

DOI
https://doi.org/10.1039/B703622A
Article type
Communication
Submitted
09 Mac 2007
Accepted
22 Mac 2007
First published
02 Apr 2007

CrystEngComm, 2007,9, 456-459

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The first example of a coordination polymer from the expanded 4,4′-bipyridine ligand [Ru(pytpy)2]2+ (pytpy = 4′-(4-pyridyl)-2,2′∶6′,2″-terpyridine)

J. E. Beves, E. C. Constable, C. E. Housecroft, C. J. Kepert and D. J. Price, CrystEngComm, 2007, 9, 456 DOI: 10.1039/B703622A

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