Issue 65, 2024
From the journal:

Chemical Communications

Nitroso-azomethine(ene) reaction enabled annulations of nitrosoarenes, azomethines and alkenes†

Anisha Purkait,a   Surya Veer Singh Pal,a   Kaushik Soni,a   Kalishankar Bhattacharyya ORCID logo *a  and  Chandan K. Jana ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Assam 781039, India
E-mail: ksb@iitg.ac.in, ckjana@iitg.ac.in

Abstract

An unprecedented example of a nitroso-azomethine(ene) reaction is reported. Nitroso-azomethine(ene) reaction-mediated unprecedented annulation of nitrosoarenes, azomethines, and alkenes to furnish arylquinolines via arene functionalization of nitrosoarene has been developed. DFT studies provided mechanistic insights into the newly developed nitroso-azomethine(ene) reaction.

Graphical abstract: Nitroso-azomethine(ene) reaction enabled annulations of nitrosoarenes, azomethines and alkenes

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Article information

DOI
https://doi.org/10.1039/D4CC02117G
Article type
Communication
Submitted
01 Mei 2024
Accepted
08 Jul 2024
First published
10 Jul 2024

Chem. Commun., 2024,60, 8541-8544

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Nitroso-azomethine(ene) reaction enabled annulations of nitrosoarenes, azomethines and alkenes

A. Purkait, S. V. S. Pal, K. Soni, K. Bhattacharyya and C. K. Jana, Chem. Commun., 2024, 60, 8541 DOI: 10.1039/D4CC02117G

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