Ba8SrPb24O24Cl18: the first alkali-earth metal lead(II) oxyhalide with an intriguing multimember-ring layer

Zhuang Li; Shengzi Zhang; Wenhao Xing; Zheshuai Lin; Jiyong Yao; Yicheng Wu

doi:10.1039/C9DT02839K

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Ba₈SrPb₂₄O₂₄Cl₁₈: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer†

Zhuang Li,

^abc Shengzi Zhang,^ac Wenhao Xing,^abc Zheshuai Lin,^a Jiyong Yao

*^ab and Yicheng Wu^ad

Author affiliations

* Corresponding authors

^a Beijing Center for Crystal Research and Development, Key Lab of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
E-mail: jyao@mail.ipc.ac.cn

^b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^c University of Chinese Academy of Sciences, Beijing 100049, P. R. China

^d Institute of Functional Crystal Materials, Tianjin University of Technology, Tianjin 300384, P.R. China

Abstract

The first alkali-earth metal lead(II) oxyhalide Ba₈SrPb₂₄O₂₄Cl₁₈ characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba₈SrPb₂₄O₂₄Cl₁₈ exhibits a moderate band gap of 3.09 eV, incongruent melting behavior and birefringence of 0.014@1064 nm. This discovery may offer new ideas for regulating the optical properties of oxyhalides and broadening their structural diversity.

This article is part of the themed collection: Inorganic Porous and Layered Material

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Article information

DOI: https://doi.org/10.1039/C9DT02839K
Article type: Communication
Submitted: 09 Jul 2019
Accepted: 17 Ago 2019
First published: 19 Ago 2019

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Dalton Trans., 2020,49, 3667-3671

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Ba₈SrPb₂₄O₂₄Cl₁₈: the first alkali-earth metal lead(II) oxyhalide with an intriguing multimember-ring layer

Z. Li, S. Zhang, W. Xing, Z. Lin, J. Yao and Y. Wu, Dalton Trans., 2020, 49, 3667 DOI: 10.1039/C9DT02839K

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