Issue 10, 2019

MXene-derived TiO2/reduced graphene oxide composite with an enhanced capacitive capacity for Li-ion and K-ion batteries

Abstract

Li-ion and K-ion batteries present their unique advantages of high energy density and low cost, respectively. It is a challenge to explore a universal anode with efficient electrochemical performance. Herein, a two-dimensional TiO2/reduced graphene oxide (RGO) composite was prepared by a facile hydrothermal method. TiO2 nanoparticles are transformed from Ti2C MXene and connect the RGO nanosheets to form a sheet-like structure. Serving as the anode material, the TiO2/RGO presents high capacity, remarkable rate ability and long cycling performance for both Li- and K-ion batteries. The superior electrochemical performance is attributed to the short ion diffusion path due to the small particle size (15–25 nm) and the highway for electron transport provided by RGO. In addition, RGO motivates the capacitive contribution, resulting in enhanced capacity and better rate performance. Meanwhile, the electrochemical kinetics of Li/K-ion storage was investigated by quantitative kinetics analysis. This work demonstrates a possibility to introduce the capacitive capacity to realize rapid ion storage and improve the cycling stability, providing a new strategy to design efficient electrodes for metal-ion batteries.

Graphical abstract: MXene-derived TiO2/reduced graphene oxide composite with an enhanced capacitive capacity for Li-ion and K-ion batteries

Supplementary files

Article information

Article type
Paper
Submitted
14 Des 2018
Accepted
25 Jan 2019
First published
29 Jan 2019

J. Mater. Chem. A, 2019,7, 5363-5372

MXene-derived TiO2/reduced graphene oxide composite with an enhanced capacitive capacity for Li-ion and K-ion batteries

Y. Fang, R. Hu, B. Liu, Y. Zhang, K. Zhu, J. Yan, K. Ye, K. Cheng, G. Wang and D. Cao, J. Mater. Chem. A, 2019, 7, 5363 DOI: 10.1039/C8TA12069B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements