Issue 19, 2019
From the journal:

Dalton Transactions

Successive carbene insertion into 9-phenyl-9-borafluorene†

Tyler A. Bartholome,a   Kristen R. Bluera  and  Caleb D. Martin ORCID logo *a  

* Corresponding authors

a Baylor University, Department of Chemistry and Biochemistry, One Bear Place #97348, Waco, TX 76798, USA
E-mail: caleb_d_martin@baylor.edu

Abstract

The reactions of 9-phenyl-9-borafluorene with trimethylsilyldiazomethane in a 1 : 1 and 1 : 2 stoichiometry furnished the corresponding BC5 and BC6 heterocycles via the formal insertion of one and two carbene units.

Graphical abstract: Successive carbene insertion into 9-phenyl-9-borafluorene

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Article information

DOI
https://doi.org/10.1039/C9DT01032G
Article type
Communication
Submitted
09 Mac 2019
Accepted
26 Mac 2019
First published
27 Mac 2019

Dalton Trans., 2019,48, 6319-6322

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Successive carbene insertion into 9-phenyl-9-borafluorene

T. A. Bartholome, K. R. Bluer and C. D. Martin, Dalton Trans., 2019, 48, 6319 DOI: 10.1039/C9DT01032G

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