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Abstract | Cited by

The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.

Graphical abstract: Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions

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