Issue 20, 2017
From the journal:

Green Chemistry

Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst†

A. P. C. Ribeiro, ORCID logo a   L. M. D. R. S. Martins ORCID logo *ab  and  A. J. L. Pombeiro ORCID logo a  

* Corresponding authors

a Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal

b Chemical Engineering Department, Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de Lisboa, Rua Conselheiro Emídio Navarro, 1959-007 Lisboa, Portugal
E-mail: lmartins@deq.isel.ipl.pt

Abstract

The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 × 103) directly from carbon dioxide is achieved by using H2 and the iron(II) scorpionate catalyst [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.

Graphical abstract: Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst

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Article information

DOI
https://doi.org/10.1039/C7GC01993A
Article type
Paper
Submitted
03 Jul 2017
Accepted
30 Ago 2017
First published
30 Ago 2017

Green Chem., 2017,19, 4811-4815

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Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

A. P. C. Ribeiro, L. M. D. R. S. Martins and A. J. L. Pombeiro, Green Chem., 2017, 19, 4811 DOI: 10.1039/C7GC01993A

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