Issue 70, 2014

Nanoscale insight into C–C coupling on cobalt nanoparticles

Abstract

The Ullmann coupling of bromobenzene to biphenyl on Co nanoparticles proceeds below room temperature via an intermediate in which phenyl groups are bound directly to metallic Co. A similar surface-bound benzyl intermediate is observed for coupling of benzylbromide to bibenzyl on Co.

Graphical abstract: Nanoscale insight into C–C coupling on cobalt nanoparticles

Supplementary files

Article information

Article type
Communication
Submitted
14 Mei 2014
Accepted
13 Jul 2014
First published
14 Jul 2014

Chem. Commun., 2014,50, 10035-10037

Nanoscale insight into C–C coupling on cobalt nanoparticles

E. A. Lewis, C. J. Murphy, A. Pronschinske, M. L. Liriano and E. C. H. Sykes, Chem. Commun., 2014, 50, 10035 DOI: 10.1039/C4CC03678F

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