Issue 45, 2013
From the journal:

CrystEngComm

Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control†

Zhi He,‡a   Qingqing Pang,‡a   Damien Rankine,b   Christopher J. Sumby,b   Lijuan Zhang,*c   Christian J. Doonan*b  and  Qiaowei Li*a  

* Corresponding authors

a Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China
E-mail: qwli@fudan.edu.cn

b School of Chemistry and Physics, The University of Adelaide, SA 5005, Australia
E-mail: christian.doonan@adelaide.edu.au

c Laboratory of Advanced Materials, Fudan University, 2205 Songhu Road, Shanghai 200433, China
E-mail: zhanglijuan@fudan.edu.cn

Abstract

Organic links of varied structure metrics and functionalities connect with Cu2(COO)4 clusters to afford layered metal–organic frameworks. Through topological and pore control, polyoxometalates could be synthetically encapsulated within the cavities. The templating effects of polyoxometalates and specific link functionalizations provide two strategies for controllably incorporating these active species into frameworks.

Graphical abstract: Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control

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Article information

DOI
https://doi.org/10.1039/C3CE41136B
Article type
Communication
Submitted
13 Jun 2013
Accepted
29 Jul 2013
First published
28 Ago 2013

CrystEngComm, 2013,15, 9340-9343

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Encapsulation of polyoxometalates within layered metal–organic frameworks with topological and pore control

Z. He, Q. Pang, D. Rankine, C. J. Sumby, L. Zhang, C. J. Doonan and Q. Li, CrystEngComm, 2013, 15, 9340 DOI: 10.1039/C3CE41136B

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