Enantioselective total synthesis of (+)-galbulinvia organocatalytic domino Michael–Michael–aldol condensation

Bor-Cherng Hong; Che-Sheng Hsu; Gene-Hsiang Lee

doi:10.1039/C2CC16682H

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Enantioselective total synthesis of (+)-galbulinvia organocatalytic domino Michael–Michael–aldol condensation†‡

Bor-Cherng Hong,*^a Che-Sheng Hsu^a and Gene-Hsiang Lee^b

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* Corresponding authors

^a Department of Chemistry and Biochemistry, National Chung Cheng University, Taiwan, R.O.C
E-mail: chebch@ccu.edu.tw
Fax: +886 5 2721040
Tel: +886 5 2428174

^b Instrumentation Center, National Taiwan University, Taipei, Taiwan, R.O.C.

Abstract

A concise and practical enantioselective synthesis of (+)-galbulin has been achieved using organocatalytic domino Michael–Michael–aldol condensation and organocatalytic kinetic resolution as the key steps.

This article is part of the themed collection: Organocatalysis

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Article information

DOI: https://doi.org/10.1039/C2CC16682H
Article type: Communication
Submitted: 28 Okt 2011
Accepted: 29 Nov 2011
First published: 01 Des 2011

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Chem. Commun., 2012,48, 2385-2387

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Enantioselective total synthesis of (+)-galbulinvia organocatalytic domino Michael–Michael–aldol condensation

B. Hong, C. Hsu and G. Lee, Chem. Commun., 2012, 48, 2385 DOI: 10.1039/C2CC16682H

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Chemical Communications

Enantioselective total synthesis of (+)-galbulinvia organocatalytic domino Michael–Michael–aldol condensation†‡

Abstract

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Enantioselective total synthesis of (+)-galbulinvia organocatalytic domino Michael–Michael–aldol condensation

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