Issue 26, 2010

Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2

Abstract

By introducing SO2 as the sulfur source, the synthesis of an extensive family of cluster endohedral fullerenes Sc2S@C2n (n = 40–50) was demonstrated and a new isomer of Sc2S@C82 (Cs : 6) was isolated and characterized by spectroscopic and electrochemical methods for the first time.

Graphical abstract: Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2

Supplementary files

Article information

Article type
Communication
Submitted
09 Apr 2010
Accepted
07 Mei 2010
First published
25 Mei 2010

Chem. Commun., 2010,46, 4818-4820

Synthesis of a new endohedral fullerene family, Sc2S@C2n (n = 40–50) by the introduction of SO2

N. Chen, M. N. Chaur, C. Moore, J. R. Pinzón, R. Valencia, A. Rodríguez-Fortea, J. M. Poblet and L. Echegoyen, Chem. Commun., 2010, 46, 4818 DOI: 10.1039/C0CC00835D

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