Issue 38, 2009

Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

Abstract

Five-coordinate boryl complexes relevant to Ir mediated C–H borylations have been synthesized, providing a glimpse of the most fundamental step in the catalytic cycle for the first time.

Graphical abstract: Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
21 Jul 2009
Accepted
17 Ago 2009
First published
04 Sep 2009

Chem. Commun., 2009, 5731-5733

Getting the sterics just right: a five-coordinate iridium trisboryl complex that reacts with C–H bonds at room temperature

G. A. Chotana, B. A. Vanchura, II, M. K. Tse, R. J. Staples, R. E. Maleczka, Jr and M. R. Smith, III, Chem. Commun., 2009, 5731 DOI: 10.1039/B914736E

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