Harnessing the reactivity of captodative radicals: photocatalytic α-pyridination of glycyl derivatives through reversible radical coupling

Ken Yamazaki, Shuta Akimoto and Tomoya Miura

Org. Biomol. Chem., 2025, 23, 9936
DOI: 10.1039/D5OB00675A

An asymmetric biomimetic aldol reaction of glycinate with aliphatic aldehydes for efficient synthesis of chiral β-hydroxy-α-amino acid esters

Tao Liu, Dong Ma, Mingming Lu, Ting Ma, Siqi Liu, Guoqing Zhao and Baoguo Zhao

Org. Chem. Front., 2025, 12, 6139
DOI: 10.1039/D5QO00653H

Photoredox-catalyzed nucleophilic addition of α-amino radicals to unsaturated compounds

Xu Ha, Yuze Hua and Guo-Qiang Xu

Chem. Commun., 2025, 61, 17989
DOI: 10.1039/D5CC04974A

Sequential oxidative dearomatization/asymmetric homologation: from simple naphthols to chiral benzocycloheptanes

Hongkun Zeng, Shiyang Li, Lichao Ning, Tao Huang, Xiaoming Feng and Lili Lin

Chem. Sci., 2025, 16, 22536
DOI: 10.1039/D5SC05865A

Synergistic catalytic allenylic alkylation for stereodivergent construction of allenes bearing 1,3-axial and central chirality

Min Chen, Yuzhen Li, Jun He, Lili Lin, Liang-Wen Feng and Xiaohua Liu

Org. Chem. Front., 2025, 12, 4930
DOI: 10.1039/D5QO00467E

Chiral ruthenium complex/Ph 2 P(2-furyl)–catalyzed asymmetric nucleophilic addition of aryl aldehyde hydrazones to simple ketones

Chenghao Zhu, Zihao Ye, Haining Wang, Da Ma, Zhiming Li, Chao-Jun Li and Junliang Zhang

Sci. Adv., 2025, 11
DOI: 10.1126/sciadv.adv0095

Catalytic Enantioselective Methods for Synthesis of 1,2-Amino Tertiary Alcohols and Their Analogues

Steven J. Malcolmson and Faraan Rahim

Chem. Rev., 2025, 125, 10765
DOI: 10.1021/acs.chemrev.5c00435

Photoexcited Hantzsch Ester and Cobalt Catalysis Enable Diastereo- and Enantioselective Allylation of Aldehydes

Junjie Xue, Jiaming Zou, Shen Gao, Qingshu Zheng, Weiwei Fang and Jiawang Liu

ACS Catal., 2025, 15, 6165
DOI: 10.1021/acscatal.5c01060

Asymmetric Catalytic Radical Reactions Enabled by Chiral N,N′-Dioxide–Metal Complexes

Weidi Cao, Xiaohua Liu and Xiaoming Feng

Acc. Chem. Res., 2025, 58, 2496
DOI: 10.1021/acs.accounts.5c00370

Alkyl-Trifluoromethylation of Glycine Derivatives

Chenxing Zhou, Xudong Wang, Peng Kong, Dongsheng Ji, Pengxin Zhou and Congde Huo

Org. Lett., 2025, 27, 7126
DOI: 10.1021/acs.orglett.5c02028

Iridium-Catalyzed Photoredox Functionalization of Glycine Derivatives

Synfacts, 2024, 20, 1332
DOI: 10.1055/a-2439-7359

Asymmetric Cross-Dehydrogenative Coupling of Glycinates via Iodine-Mediated Photoredox/Lewis Acid Synergistic Catalysis

Jiuqi Tan, Hanyu Su, Min Chen, Fengnan Xiao, Longqing Yang, Xiaoming Feng, Liang-Wen Feng and Xiaohua Liu

ACS Catal., 2025, 15, 9633
DOI: 10.1021/acscatal.5c02808

Thiophenol-Catalyzed Visible-Light-Mediated Oxidative Cleavage of C=C Bond of Alkene

Wenjing Li, Liyan Yang, Li Guan, Xuejiao Zhang, Jing You, Siyu Shen, Yuqi Zhao and Chen Duan

Acta Chimica Sinica, 2025, 83, 596
DOI: 10.6023/A25030064

Oxidative Couplings of N-Aryl Peptides in Organic Solvent: Preventing Amino Acid Side Chain Loss

Karlee C. McKinney, Ellen J. T. Warner, Hailey A. Young, Sheba C. Gage and Caroline Proulx

Org. Lett., 2025, 27, 6527
DOI: 10.1021/acs.orglett.5c01986

Chiral Lewis Acid-Catalyzed Intramolecular [2 + 2] Photocycloaddition: Enantioselective Synthesis of Azaarene-Functionalized Azabicyclo[2.1.1]hexanes and Bicyclo[1.1.1]pentanes

Dong Tian, Yixing Pan, Xiaowei Zhao, Yanli Yin and Zhiyong Jiang

J. Am. Chem. Soc., 2025, 147, 12410
DOI: 10.1021/jacs.5c03542

Photoinduced Asymmetric [4 + 2] Cycloaddition of Benzocyclobutenones with Ketones into 3,4-Dihydroisocoumarins

Hansen Zhao, Xi Lu, Liangkun Yang, Sile Li, Xiaoming Feng and Weidi Cao

Org. Lett., 2025, 27, 8656
DOI: 10.1021/acs.orglett.5c02591

Visible Light‐Promoted Enantioselective Catalytic Alkylation of α‐Ketoamides with Hydrocarbons

Han Yu, Zun Yang, Hongda Wu, Yao Luo, Weidi Cao, Xiaohua Liu and Xiaoming Feng

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202402112