Issue 4, 2020

Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

Abstract

Continuous reductive amination of aldehydes with nitroarenes over a Pd–Pt–Fe3O4 catalyst was performed. We used NH3BH3 as not only a hydrogen source for nitro reduction, but also a reductant for imine reduction. Secondary aromatic amines were obtained in the continuous flow reaction in good to excellent yields.

Graphical abstract: Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

Supplementary files

Article information

Article type
Paper
Submitted
08 okt 2019
Accepted
09 dec 2019
First published
09 dec 2019

Catal. Sci. Technol., 2020,10, 944-949

Simple reversible fixation of a magnetic catalyst in a continuous flow system: ultrafast reduction of nitroarenes and subsequent reductive amination using ammonia borane

H. W. Kim, S. Byun, S. M. Kim, H. J. Kim, C. Lei, D. Y. Kang, A. Cho, B. M. Kim and J. K. Park, Catal. Sci. Technol., 2020, 10, 944 DOI: 10.1039/C9CY02021G

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