Issue 76, 2012

A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour

Abstract

The new Al-based metal–organic framework [Al13(OH)27(H2O)6(BDC-NH2)3Cl6(C3H7OH)6] denoted CAU-6 (CAU = Christian-Albrechts-Universität) was solvothermally synthesized in 2-propanol and was thoroughly characterized. The framework structure exhibits a unique column-shaped inorganic building unit, which is based on stacked, corner-sharing Al13-clusters. The compound exhibits unprecedented hydrophilicity for metal–organic frameworks.

Graphical abstract: A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour

Supplementary files

Article information

Article type
Communication
Submitted
09 jul 2012
Accepted
07 aug 2012
First published
08 aug 2012

Chem. Commun., 2012,48, 9486-9488

A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour

H. Reinsch, B. Marszałek, J. Wack, J. Senker, B. Gil and N. Stock, Chem. Commun., 2012, 48, 9486 DOI: 10.1039/C2CC34909D

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