Issue 79, 2012

Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

Abstract

The synthesis and successful activation of IRMOF-8 (Zn4O(ndc)3, ndc = naphthalene-2,6-dicarboxylate) is presented. Room temperature synthesis effectively suppresses interpenetration. Although conventional activation under reduced pressure leads to structural collapse, activation by flowing supercritical CO2 yields a guest-free material with a BET surface area of 4461 m2 g−1.

Graphical abstract: Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

Supplementary files

Article information

Article type
Communication
Submitted
30 jun 2012
Accepted
12 aug 2012
First published
29 aug 2012

Chem. Commun., 2012,48, 9828-9830

Non-interpenetrated IRMOF-8: synthesis, activation, and gas sorption

J. I. Feldblyum, A. G. Wong-Foy and A. J. Matzger, Chem. Commun., 2012, 48, 9828 DOI: 10.1039/C2CC34689C

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