Issue 78, 2024

Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

Abstract

Herein we report a strategy for the synthesis of organosilicons, including siloxanes, silyl ethers, and aminosilanes, via Co-catalyzed dehydrogenative coupling between hydrosilanes and nucleophiles. This discovery represents an expansion of the synthetic toolkit for organosilicon synthesis, forging Si–O and Si–N bonds in the presence of cobalt complexes with salen-type ligands.

Graphical abstract: Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

Supplementary files

Article information

Article type
Communication
Submitted
16 aug 2024
Accepted
04 sep 2024
First published
05 sep 2024

Chem. Commun., 2024,60, 10886-10889

Streamlining Si–O bond formation through cobalt-catalyzed dehydrocoupling

E. Szafoni, D. Lewandowski, M. Gruszczyński, K. Broniarz, H. Stachowiak-Dłużyńska, K. Kuciński and G. Hreczycho, Chem. Commun., 2024, 60, 10886 DOI: 10.1039/D4CC04144E

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