Issue 73, 2024

Reactivity of a triamidoamine terminal uranium(vi)-nitride with 3d-transition metal metallocenes

Abstract

Reactions between [(TrenTIPS)UVI[triple bond, length as m-dash]N] (1, TrenTIPS = {N(CH2CH2NSiPri3)3}3−) and [MII5-C5R5)2] (M/R = Cr/H, Mn/H, Fe/H, Ni/H) were intractable, but M/R = Co/H or Co/Me afforded [(TrenTIPS)UV[double bond, length as m-dash]N-(η14-C5H5)CoI5-C5H5)] (2) and [(TrenTIPS)UIV–NH2] (3), respectively. For M/R = V/H [(TrenTIPS)UIV–N[double bond, length as m-dash]VIV5-C5H5)2] (4), was isolated. Complexes 2–4 evidence one-/two-electron uranium reductions, nucleophilic nitrides, and partial N-atom transfer.

Graphical abstract: Reactivity of a triamidoamine terminal uranium(vi)-nitride with 3d-transition metal metallocenes

Supplementary files

Article information

Article type
Communication
Submitted
30 jul 2024
Accepted
13 aug 2024
First published
15 aug 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 9990-9993

Reactivity of a triamidoamine terminal uranium(VI)-nitride with 3d-transition metal metallocenes

J. A. Seed, P. A. Cleaves, G. R. Hatton, D. M. King, F. Tuna, A. J. Wooles, N. F. Chilton and S. T. Liddle, Chem. Commun., 2024, 60, 9990 DOI: 10.1039/D4CC03846K

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements