Issue 44, 2013

Halogen- and hydrogen-bonding triazole-functionalised porphyrin-based receptors for anion recognition

Abstract

Iodotriazole and triazole anion recognition groups have been integrated into a picket-fence zinc(II)-metalloporphyrin scaffold to produce receptors for anion recognition and sensing applications. 1H NMR and UV/visible spectroscopic investigations reveal both host systems exhibit strong anion binding affinities in a range of solvent media. Importantly, the halogen-bonding iodotriazole-containing porphyrin-based host displays halide binding affinities substantially larger than the protic-functionalised analogue concomitant with a reduced strength of oxoanion complexation.

Graphical abstract: Halogen- and hydrogen-bonding triazole-functionalised porphyrin-based receptors for anion recognition

Supplementary files

Article information

Article type
Paper
Submitted
01 aug 2013
Accepted
10 sep 2013
First published
10 sep 2013
This article is Open Access
Creative Commons BY license

Dalton Trans., 2013,42, 15766-15773

Halogen- and hydrogen-bonding triazole-functionalised porphyrin-based receptors for anion recognition

L. C. Gilday, N. G. White and P. D. Beer, Dalton Trans., 2013, 42, 15766 DOI: 10.1039/C3DT52093E

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