Themed collection Sustainable Energy & Fuels Emerging Investigators Series

21 items
Perspective

Selective hydrogenation of lignocellulosic biomass over single-atom catalysts

Single-atom catalysis for lignocellulosic biomass refinery for fuels and chemicals provides a new insight and improved catalytic performances for the sustainable development of the society.

Graphical abstract: Selective hydrogenation of lignocellulosic biomass over single-atom catalysts
Open Access Review Article

Design of nanostructured 2D (photo-)electrocatalysts for biomass valorization coupled with H2 production

A comprehensive review of advanced design strategies of nanostructured 2D electrodes for sustainable biomass valorization coupled with the HER.

Graphical abstract: Design of nanostructured 2D (photo-)electrocatalysts for biomass valorization coupled with H2 production
Communication

In situ growth of a heterojunction CdS/TiO2 nanofiber monolithic photocatalyst sheet for enhanced hydrogen evolution

A heterojunction CdS/TiO2 nanofiber monolithic photocatalyst sheet was developed via facile in situ hydrothermal growth on Ti foil. The photocatalyst sheet can greatly enhance photocatalytic H2 production.

Graphical abstract: In situ growth of a heterojunction CdS/TiO2 nanofiber monolithic photocatalyst sheet for enhanced hydrogen evolution
Communication

Oxalate metal–organic framework derived atomic Ru3+-doped Co(OH)2 nanosheets for a highly efficient hydrogen evolution reaction

Oxalate metal–organic framework derived atomic Ru3+-doped Co(OH)2 nanosheets are fabricated for highly efficient hydrogen evolution reaction, showing a very small overpotential of 36 mV at 30 mA cm−2 in 1.0 M KOH.

Graphical abstract: Oxalate metal–organic framework derived atomic Ru3+-doped Co(OH)2 nanosheets for a highly efficient hydrogen evolution reaction
Communication

In situ oxidative etching-enabled synthesis of hollow Cu2O nanocrystals for efficient CO2RR into C2+ products

The prepared hollow Cu2O nanocrystals via oxidative etching yield C2+ products with a faradaic efficiency of 75.9% and a C2+ partial current density of 0.54 A cm−2 ascribed to their defect-rich sites and abundant stepped facets.

Graphical abstract: In situ oxidative etching-enabled synthesis of hollow Cu2O nanocrystals for efficient CO2RR into C2+ products
Paper

Scalable post-treatment for improved self-assembled monolayer coverage in perovskite solar cells

The Cooled Moisture Condensation (CMC) process improves MeO–2PACz coverage on FTO by increasing surface hydroxyl groups and minimizing oxygen vacancies, resulting in more uniform self-assembled monolayer coverage and enhanced solar cell performance.

Graphical abstract: Scalable post-treatment for improved self-assembled monolayer coverage in perovskite solar cells
Open Access Paper

Decentralised production of e-fuels for aviation: implications and trade-offs of a targeted small-scale production of sustainable aviation fuel based on Fischer–Tropsch synthesis

The introduction of Sustainable Aviation Fuel (SAF) is expected to play an important role in the decarbonisation of the aviation sector.

Graphical abstract: Decentralised production of e-fuels for aviation: implications and trade-offs of a targeted small-scale production of sustainable aviation fuel based on Fischer–Tropsch synthesis
From the themed collection: Recent Open Access Articles
Paper

Nickel single atom catalyst supported on the gallium nitride monolayer: first principles investigations on the decisive role of support in the electrocatalytic reduction of CO2

First principles investigations on the modulation of electronic structure of Ni based SAC by varrying the nature and type of support for CO2 reduction to C1 products.

Graphical abstract: Nickel single atom catalyst supported on the gallium nitride monolayer: first principles investigations on the decisive role of support in the electrocatalytic reduction of CO2
Paper

Energy-dense anode-free rechargeable lithium metal batteries based on thick cathodes and pulse charging strategies

In combination with a thick cathode and pulse charging strategies, anode-free lithium metal batteries demonstrated reduced polarization at 5 mA cm−2 and a capacity retention of 79.4% after 50 cycles.

Graphical abstract: Energy-dense anode-free rechargeable lithium metal batteries based on thick cathodes and pulse charging strategies
Paper

Methylated precursor leads to carbon nitride (CNx) with improved interfacial interactions for enhanced photocatalytic performance

Methylated precursors used in a facile CNx copolymerization synthesis yield modified CNx materials with better aqueous dispersibility properties for enhanced photoactivity.

Graphical abstract: Methylated precursor leads to carbon nitride (CNx) with improved interfacial interactions for enhanced photocatalytic performance
Paper

Sector coupling leading to low-carbon production of power and chemicals in China

A pathway to a carbon-neutral electricity-chemical nexus in China by 2060 is attainable. Sector coupling reduces fossil power generation by 10%, drives renewable curtailment rates to below 5%, and expands energy transmission capacity by at most 18%.

Graphical abstract: Sector coupling leading to low-carbon production of power and chemicals in China
From the themed collection: Spotlight on Women in Energy
Paper

Optimal design of a coupled photovoltaic–electrolysis-battery system for hydrogen generation

A computational algorithm to model a coupled solar-hydrogen system is presented. The results demonstrated that optimizing the system's cost and hydrogen production rate implicitly ensures the levelized cost of energy is minimized.

Graphical abstract: Optimal design of a coupled photovoltaic–electrolysis-battery system for hydrogen generation
Paper

Subsurface oxygen reduction reaction activity on Ti2N MXene revealed by in situ Raman spectroelectrochemistry

In situ Raman spectroscopy reveals that the subsurface of Ti2N nitride MXene is the active site for oxygen reduction reaction. We also report that the Ti2N MXene is more active than Ti3C2 MXene and more stable than Ti3C2 and 10% Pt/C.

Graphical abstract: Subsurface oxygen reduction reaction activity on Ti2N MXene revealed by in situ Raman spectroelectrochemistry
Paper

Stable Cs2ReX6 (X – Cl, Br) vacancy-ordered perovskites for solar water splitting

We report one of the most stable vacancy-ordered perovskites Cs2ReX6 (X – Cl, Br) that show panchromatic visible absorption and demonstrated excellent acid/base stability, which enabled them to be employed as photoanodes for solar water oxidation.

Graphical abstract: Stable Cs2ReX6 (X – Cl, Br) vacancy-ordered perovskites for solar water splitting
Open Access Paper

Supported rhenium catalysts for the hydrogenation of levulinic acid derivatives: limits and potential

Levulinic acid derivatives, such as alkyl levulinates, are suitable starting reactants for the production of fuel components, namely γ-valerolactone (GVL), alkyl valerates, pentanol, and pentylvalerate (PV).

Graphical abstract: Supported rhenium catalysts for the hydrogenation of levulinic acid derivatives: limits and potential
From the themed collection: Recent Open Access Articles
Paper

PEO composite solid polymer electrolytes with the synergistic effect of cryogenic engineering and trace BP nanosheets for nearly room temperature and 4 V class all-solid-state lithium batteries

A novel PEO-based SPE with a synergistic effect of black phosphorus (BP) nanosheets and a cryogenic method, which can combine the advantages of the fast Li+ pathways of BP nanosheets and the low PEO crystallization of cryogenic method.

Graphical abstract: PEO composite solid polymer electrolytes with the synergistic effect of cryogenic engineering and trace BP nanosheets for nearly room temperature and 4 V class all-solid-state lithium batteries
Paper

Tuning B–N pairs in porous carbon nanorods for electrochemical conversion of CO2 to syngas with controllable CO/H2 ratios

Through modulating the contents of the N/B dopants and corresponding B–N pairs for the NBCs, the syngas generation with tunable CO/H2 ratios from 12.3 to 1 under different potentials can be realized.

Graphical abstract: Tuning B–N pairs in porous carbon nanorods for electrochemical conversion of CO2 to syngas with controllable CO/H2 ratios
Paper

The surface-sulphurated Co3O4 nanowire array electrocatalyst for oxygen evolution reaction and water-splitting applications

A surface-sulphurated cobalt oxide electrocatalyst with a nanowire array integrated structure is designed for oxygen evolution reaction and water-splitting applications.

Graphical abstract: The surface-sulphurated Co3O4 nanowire array electrocatalyst for oxygen evolution reaction and water-splitting applications
Paper

Phase junction crystalline carbon nitride nanosheets modified with CdS nanoparticles for photocatalytic CO2 reduction

PTI–melon molecular junctions anchored with CdS nanoparticles enable efficient CO2 photoreduction, affording a high AQE of 10.8% at 420 nm.

Graphical abstract: Phase junction crystalline carbon nitride nanosheets modified with CdS nanoparticles for photocatalytic CO2 reduction
Paper

Out-of-plane transient thermal conductivity measurements for bulk semiconducting conjugated polymers using fast scanning calorimetry

The thermal conductivity for CP was enhanced with 5 wt% dopants but impaired with more than 20 wt% dopants. The enhanced thermal conductivity was attributed to higher rDOC and stronger π–π interactions due to small amount of active dopants.

Graphical abstract: Out-of-plane transient thermal conductivity measurements for bulk semiconducting conjugated polymers using fast scanning calorimetry
Paper

Creating an electron-rich region on ultrafine Bi2O3 nanoparticles to boost the electrochemical carbon dioxide reduction to formate

Metal–support interfacial interactions can enrich the electron density of Bi2O3 effectively facilitating *COO intermediate generation and boosting catalytic activity.

Graphical abstract: Creating an electron-rich region on ultrafine Bi2O3 nanoparticles to boost the electrochemical carbon dioxide reduction to formate
21 items

About this collection

Sustainable Energy & Fuels is proud to present our Emerging Investigators Series, highlighting the very best work from researchers in the early stages of their independent careers.

The collection showcases research from early career energy scientists who are working towards making future energy technologies more sustainable, in line with UN Sustainable Development Goal 7 and the scope of Sustainable Energy & Fuels. Congratulations to all the featured researchers!

This collection will be updated when new Emerging Investigator Series papers are published – so keep checking this page and watch the collection grow.

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