Reversible complexation mediated polymerization (RCMP) was developed as a new class of controlled radical polymerization (CRP) using organic catalysts. In particular, photo-RCMP is among the simplest, cheapest, and most robust photoinduced CRPs.
A nano-capsule synthesized via self-catalyzed RCMP and its use as a heterogeneous catalyst and a nano-reactor of RCMP to generate a multi-elemental particle.
A novel alkyl iodide bearing an azlactone group was successfully employed as a reversible complex-mediated polymerization (RCMP) initiator for synthesizing for the first-time well-defined α-azlactone-terminated polymethacrylates (Đ < 1.30). The amine-scavenging ability of the resulting functional polymers was demonstrated by using benzylamine.
An ionic heterogeneous catalyst, TD-I, was developed for the RCMP of PPEGMA in aqueous solution under white LED irradiation.
We successfully synthesized a catalyst with a wide absorption range (300–1000 nm) for controlled radical polymerization of PEGMA in aqueous solution and MMA in bulk under the irradiation of white, blue, green, red, and NIR LED light, and sunlight.