Metal–organic framework-derived semiconductors for photocatalytic hydrogen production

Emmanuel Nyela Musa and Kyriakos C. Stylianou

Mol. Syst. Des. Eng., 2023, 8, 151
DOI: 10.1039/D2ME00221C

Dual promotional effect of CuxO clusters grown with atomic layer deposition on TiO2 for photocatalytic hydrogen production

Saeed Saedy, Nico Hiemstra, Dominik Benz, Hao Van Bui, Michael Nolan and J. Ruud van Ommen

Catal. Sci. Technol., 2022, 12, 4511
DOI: 10.1039/D2CY00400C

Bimetallic Co–Mo sulfide/carbon composites derived from polyoxometalate encapsulated polydopamine-decorated ZIF nanocubes for efficient hydrogen and oxygen evolution

Zheng Huang, Zhuxian Yang, Quanli Jia, Nannan Wang, Yanqiu Zhu and Yongde Xia

Nanoscale, 2022, 14, 4726
DOI: 10.1039/D1NR07913A

Unveiling the scope and perspectives of MOF-derived materials for cutting-edge applications

Khezina Rafiq, Mamoona Sabir, Muhammad Zeeshan Abid and Ejaz Hussain

Nanoscale, 2024, 16, 16791
DOI: 10.1039/D4NR02168A

Effect of substrate and oxygen-argon ratio on photocatalytic CO2 reduction in ITO films prepared by magnetron sputtering

Xiong He, Tao Li, Fan Zhang, Limin Gao, Junhao Wu, Yubo Mao, Haiquan Xie and Kui Li

Ceramics International, 2024, 50, 19881
DOI: 10.1016/j.ceramint.2024.03.114

Highly stable bifunctional MXenes/Mn3O4/CuO nanocomposite for improved overall water-splitting

Sachin Pundir, Shagun Kainth, Akansha Mehta, Piyush Sharma and O.P. Pandey

Fuel, 2026, 415, 138447
DOI: 10.1016/j.fuel.2026.138447

Preparation of a new green magnetic Fe3O4 @TiO2-P25 photocatalyst for solar advanced oxidation processes in water

Jorge López, Ana Rey, Emilio Viñuelas-Zahinos and Pedro M. Álvarez

Journal of Environmental Chemical Engineering, 2023, 11, 109999
DOI: 10.1016/j.jece.2023.109999

Z-scheme ZnIn2S4/CuxO heterostructure on flexible substrate for efficient photothermal catalytic CO2 reduction

Jiping Shi, Liuqing Hua, Lu Ruan, Xingjian Zhang, Zhengdao Li, Fengyun Su, Xin Li, Haiquan Xie and Yong Zhou

Applied Surface Science, 2025, 680, 161369
DOI: 10.1016/j.apsusc.2024.161369

Site-Selective Synthesis of Bilayer Graphene on Cu Substrates Using Titanium as a Carbon Diffusion Barrier

Qiyang Song, Youwei Zhang, Qiao Chen, Su Wu, Xin Yan, Kai He, Guilong Gao, Qiao Chen and Shun Wang

ACS Appl. Mater. Interfaces, 2024, 16, 38355
DOI: 10.1021/acsami.4c04521

MIL‐125(Ti)‐Based Heterojunctions: Progress in Photocatalytic Applications

Shuoyu He, Yuanke Zhang, Jingjing Tian, Guixia Ling and Peng Zhang

ChemistrySelect, 2026, 11
DOI: 10.1002/slct.73561

Metal‐Organic Frameworks‐Derived Nanocarbon Materials and Nanometal Oxides for Photocatalytic Applications

Jun‐Qing Ye, Shu‐Ying Xu, Qian Liang, Yan‐Zi Dai and Ming‐Yang He

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400161

Boosting Charge Carrier Separation by Constructing a Dual Metal–Organic Framework-Derived CuO@TiO2 Heterojunction toward Efficient Visible-Light-Driven Hydrogen Production

Yi-Shan Ouyang, Su-Tao Zheng, Guo-Wei Guan and Qing-Yuan Yang

ACS Appl. Energy Mater., 2022, 5, 14455
DOI: 10.1021/acsaem.2c02993

Localized ultrafine Cu clusters within MOF-derived metal oxides for collective photochemical and photothermal H2 generation

Serene Wen Ling Ng, Kane Jian Hong Lim, Minmin Gao, Wanheng Lu, Tanmay Ghosh, Mingsheng Zhang, Sibudjing Kawi, Minghui Hong and Ghim Wei Ho

Applied Catalysis B: Environmental, 2024, 340, 123182
DOI: 10.1016/j.apcatb.2023.123182

Mini- Review on Metal Organic Frameworks for Electro Catalytic and Photo Catalytic Water Splitting

Kannan Gothandapani, Nivetha Ravi, Santhosh Ravichandran, Rakeesh Chilivery and T. Arunkumar

Top Catal, 2025
DOI: 10.1007/s11244-025-02256-z

Hydrogen production using noble metal-free metal-organic frameworks (MOFs)-derived CuO@C/TiO2

Hani Nasser Abdelhamid, Ayat Badry Aly Abdellatif and Haitham M. El-Bery

Chemical Engineering Journal, 2025, 514, 163343
DOI: 10.1016/j.cej.2025.163343

Modulation of Optical Band Gap of 2-Amino Terephthalic Acid Cu-MOFs Doped with Ag₂O and rGO

Maalathi Challa, M.R. Ambika, S.R. Usharani, Sheetal Batakurki and Basappa C. Yallur

AMR, 2022, 1173, 35
DOI: 10.4028/p-i3rcg6

Metal-organic framework derived multi-functionalized and co-doped TiO2/C nanocomposites for excellent visible-light photocatalysis

Mian Zahid Hussain, Zhuxian Yang, Ahmed M.E. Khalil, Shahzad Hussain, Saif Ullah Awan, Quanli Jia, Roland A. Fischer, Yanqiu Zhu and Yongde Xia

Journal of Materials Science & Technology, 2022, 101, 49
DOI: 10.1016/j.jmst.2021.05.052

Constructing g-C3N4/Cd1−xZnxS-Based Heterostructures for Efficient Hydrogen Production under Visible Light

Angelina V. Zhurenok, Dina V. Markovskaya, Evgeny Y. Gerasimov, Alexander S. Vokhmintsev, Ilya A. Weinstein, Igor P. Prosvirin, Svetlana V. Cherepanova, Andrey V. Bukhtiyarov and Ekaterina A. Kozlova

Catalysts, 2021, 11, 1340
DOI: 10.3390/catal11111340

Bi-metal-organic framework-derived S-scheme InP/CuO-C heterostructure for robust photocatalytic degradation of ciprofloxacin in a microfluidic photoreactor

Shima Parsaei, Marzie Rashid, Arash Ghoorchian, Kheibar Dashtian and Dariush Mowla

Chemical Engineering Journal, 2023, 475, 146448
DOI: 10.1016/j.cej.2023.146448

KLVFF oligopeptide-decorated amphiphilic cyclodextrin nanomagnets for selective amyloid beta recognition and fishing

Antonino Mazzaglia, Giuseppe Di Natale, Rita Tosto, Angela Scala, Giuseppe Sortino, Anna Piperno, Maria Pia Casaletto, Alberto Riminucci, Maria Laura Giuffrida, Placido G. Mineo, Valentina Villari, Norberto Micali and Giuseppe Pappalardo

Journal of Colloid and Interface Science, 2022, 613, 814
DOI: 10.1016/j.jcis.2022.01.051

Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient multifunctional electrocatalysts

Laicong Deng, Zhuxian Yang, Rong Li, Binling Chen, Quanli Jia, Yanqiu Zhu and Yongde Xia

Front. Chem. Sci. Eng., 2021, 15, 1487
DOI: 10.1007/s11705-021-2085-3

MOF-Derived Multi-heterostructured Composites for Enhanced Photocatalytic Hydrogen Evolution: Deciphering the Roles of Different Components

Mian Zahid Hussain, Zhuxian Yang, Bart van der Linden, Werner R. Heinz, Mounib Bahri, Ovidiu Ersen, Quanli Jia, Roland A. Fischer, Yanqiu Zhu and Yongde Xia

Energy Fuels, 2022, 36, 12212
DOI: 10.1021/acs.energyfuels.2c02319

Construction of S-scheme Zn0.2Cd0.8S/biochar aerogel architectures for boosting photocatalytic hydrogen production under sunlight irradiation

Chonghai Deng, Lulu Peng, Xiaohui Ling, Tao Wang, Rui Xu, Yibin Zhu, Chenchen Wang, Xuehui Qian, Lili Wang, Yiping Wu, Hanmei Hu and Yongsheng Han

Journal of Cleaner Production, 2023, 414, 137616
DOI: 10.1016/j.jclepro.2023.137616

3D‐Printed Metal–Organic Framework‐Derived Composites for Enhanced Photocatalytic Hydrogen Generation

Mian Zahid Hussain, Paula F. Großmann, Fabian Kohler, Tim Kratky, Laura Kronthaler, Bart van der Linden, Katia Rodewald, Bernhard Rieger, Roland A. Fischer and Yongde Xia

Solar RRL, 2022, 6
DOI: 10.1002/solr.202200552

Platinum catalysts supported on mixed-phase TiO2 coated by nitrogen-doped carbon derived from NH2-MIL-125 for methanol oxidation

Junyan Liu, Liting Xu and Xingwei Li

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 655, 129986
DOI: 10.1016/j.colsurfa.2022.129986

Upcycling biomass waste into Fe single atom catalysts for pollutant control

Xin Li, Kang Hu, Yizhe Huang, Qingqing Gu, Yuwen Chen, Bing Yang, Rongliang Qiu, Wenhao Luo, Bert M. Weckhuysen and Kai Yan

Journal of Energy Chemistry, 2022, 69, 282
DOI: 10.1016/j.jechem.2022.01.044

Pt Atomically Dispersed in Black TiO2−x/CuxO with Chiral‐Like Nanostructure for Visible‐Light H2 Generation

Cong Wang, Jingwei Li, Erwan Paineau, Hynd Remita and Mohamed Nawfal Ghazzal

Solar RRL, 2023, 7
DOI: 10.1002/solr.202200929

Surface Engineering Strategy: P-Doped Coo-3nio Synthesized by Zif on Mof for Photocatalytic Hydrogen Evolution

Teng Li, li youji, Lijun Zhang, Xuqiang Hao, Kai Wang, Guorong Wang, Xin Guo and Zhiliang Jin

SSRN Journal, 2022
DOI: 10.2139/ssrn.4096057

Enhanced photocatalytic hydrogen evolution with a Mixed-Valence iron Metal-Organic framework

Xinning Zhang, Xiaojie Ma, Yuqing Ye, Caixia Guo, Xiaojun Xu, Junwen Zhou and Bo Wang

Chemical Engineering Journal, 2023, 456, 140939
DOI: 10.1016/j.cej.2022.140939

MOFs coupled transition metals, graphene, and MXenes: Emerging electrocatalysts for hydrogen evolution reaction

Abdul Hanan, Muhammad Nazim Lakhan, Faiza Bibi, Amjad Khan, Irfan Ali Soomro, Altaf Hussain and Umair Aftab

Chemical Engineering Journal, 2024, 482, 148776
DOI: 10.1016/j.cej.2024.148776

Evoking Cooperative Geometric and Electronic Interactions at Nanometer Coherent Interfaces toward Enhanced Electrocatalysis

Huijun Song, Xiaoqiu Xu, Jingjing Chen, Yinling Zhang, Jia Zhao, Chongzhi Zhu, Hong Zhang, Yong Peng, Qiaoli Chen, Guan Sheng, Tulai Sun, Yu Han, Xiaonian Li and Yihan Zhu

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202301490

MOFs‐Derived Oxygen‐Vacancy‐Rich Cu‐CuxO/TiO2 with Dynamic Redox Cycling for Steering Hole‐Driven PMS Activation

Fukang Feng, Xiaoyu Zhang, Xinrui Han, Guangyu Wu and Weinan Xing

Small, 2026, 22
DOI: 10.1002/smll.202511722

Bimetallic NiCu catalyst derived from spent MOF adsorbent for efficient photocatalytic CO2 reduction

Longyun Zhang, Ganghua Zhou, Gaoran Chen, Heming Wang, Qian Zhao, Weiqin Yin, Jianjian Yi, Xingwang Zhu, Xiaozhi Wang and Xin Ning

Chemical Engineering Journal, 2024, 497, 154701
DOI: 10.1016/j.cej.2024.154701

Safe-and-Sustainable-by-Design Framework Based on a Prospective Life Cycle Assessment: Lessons Learned from a Nano-Titanium Dioxide Case Study

Georgios Archimidis Tsalidis, Lya G. Soeteman-Hernández, Cornelle W. Noorlander, Saeed Saedy, J. Ruud van Ommen, Martina G. Vijver and Gijsbert Korevaar

IJERPH, 2022, 19, 4241
DOI: 10.3390/ijerph19074241

Two-dimensional metal-organic frameworks for photocatalytic water splitting over TiO2

Hani Nasser Abdelhamid and Haitham M. El-Bery

Inorganic Chemistry Communications, 2025, 180, 115044
DOI: 10.1016/j.inoche.2025.115044

Metal–Organic Frameworks Derived CuxO/TiO2/C Nanocomposites with Enhanced Photocatalytic Performance

Yankun Wang, Yanqiu Zhu and Yongde Xia

Adv Energy and Sustain Res, 2026, 7
DOI: 10.1002/aesr.202500411

Emerging applications of metal-organic frameworks and derivatives in solar cells: Recent advances and challenges

Binling Chen, Zhuxian Yang, Quanli Jia, Richard J. Ball, Yanqiu Zhu and Yongde Xia

Materials Science and Engineering: R: Reports, 2023, 152, 100714
DOI: 10.1016/j.mser.2022.100714

Bismuth‐based metal‐organic frameworks and derivatives for photocatalytic applications in energy and environment: Advances and challenges

Yankun Wang, He Sun, Zhuxian Yang, Yanqiu Zhu and Yongde Xia

Carbon Neutralization, 2024, 3, 737
DOI: 10.1002/cnl2.153

Environmentally-friendly carbon nanomaterials for photocatalytic hydrogen production

Sheng Xiong, Rongdi Tang, Daoxin Gong, Yaocheng Deng, Jiangfu Zheng, Ling Li, Zhanpeng Zhou, Lihua Yang and Long Su

Chinese Journal of Catalysis, 2022, 43, 1719
DOI: 10.1016/S1872-2067(21)63994-3

The post-synthesis modification strategy promotes the selective oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid by the heterojunction B-BiVO4/CuxO

Dongfeng He, Jiaqi Li, Ruize Zhang, Jing Wang, Junrong Chen, Jiang Wang, Binbin Tan, Zhihao Zhang, Ting Yang and Wenlei Wang

Journal of Photochemistry and Photobiology A: Chemistry, 2026, 474, 116982
DOI: 10.1016/j.jphotochem.2025.116982

Z-scheme heterojunction photocatalyst: Deep eutectic solvents-assisted synthesis of Cu2O nanocluster improved hydrogen production of TiO2

Santosh V. Mohite, Shinik Kim, Changseung Lee, Jiyoung Bae and Yeonho Kim

Journal of Alloys and Compounds, 2022, 928, 167168
DOI: 10.1016/j.jallcom.2022.167168

Metal–organic frameworks and derived materials as photocatalysts for water splitting and carbon dioxide reduction

Jing Chen, Reza Abazari, Kayode Adesina Adegoke, Nobanathi Wendy Maxakato, Olugbenga Solomon Bello, Muhammad Tahir, Sehar Tasleem, Soheila Sanati, Alexander M. Kirillov and Yingtang Zhou

Coordination Chemistry Reviews, 2022, 469, 214664
DOI: 10.1016/j.ccr.2022.214664

Recent advances of Nano-photocatalysts involved in hydrogen production by water splitting

Louella Concepta Goveas, Sneha Nayak, Ramesh Vinayagam, Raja Selvaraj and Arivalagan Pugazhendhi

Fuel, 2023, 348, 128460
DOI: 10.1016/j.fuel.2023.128460

TiO2 Films with Macroscopic Chiral Nematic‐Like Structure Stabilized by Copper Promoting Light‐Harvesting Capability for Hydrogen Generation

Cong Wang, Sébastien R. Mouchet, Olivier Deparis, Jingwei Li, Erwan Paineau, Diana Dragoe, Hynd Remita and Mohamed Nawfal Ghazzal

Small, 2024, 20
DOI: 10.1002/smll.202402211

Peroxydisulfate-enhanced photocatalytic degradation of Tetracycline using NiO/α-Fe2O3-C derived from hierarchical NiFe Prussian blue analogue via seed-mediated growth

Hadis Sadeghzadeh, Darush Mowla, Milad Zarghami Qaretapeh and Kheibar Dashtian

Journal of Water Process Engineering, 2025, 78, 108665
DOI: 10.1016/j.jwpe.2025.108665

Inlaying metal-organic framework derived pancake-like TiO2 into three-dimensional BiOI for visible-light-driven generation of vanillin from sodium lignosulfonate

Jianhao Qiu, Dingliang Dai, Lu Zhang, Yichen Zhou, Lvye Yang and Jianfeng Yao

Journal of Colloid and Interface Science, 2022, 605, 648
DOI: 10.1016/j.jcis.2021.07.131

S-scheme Cu3P/TiO2 heterojunction for outstanding photocatalytic water splitting

Kexin Wang, Zhongge Luo, Bin Xiao, Tong Zhou, Jianhong Zhao, Congcong Shen, Dequan Li, Zhishi Qiu, Jin Zhang, Tianwei He and Qingju Liu

Journal of Colloid and Interface Science, 2023, 652, 1908
DOI: 10.1016/j.jcis.2023.08.174

Metal‐Organic Framework Derived Terephthalate Ligand Decorated TiO2 with Various Morphologies for Efficient Photocatalytic H2 Evolution

Pengyu Dong, Kangjie Gao, Kang Li, Haoyu Wang, Xinguo Xi and Pingyun Feng

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203917

Tailored Porous Bimetallic Nanozyme Platform for Full‐Cycle Therapeutics of Intestinal Ischemia/Reperfusion

Chenghao Qiu, Wenjing Xian, Mengxue Wang, Guozhi Zhao, Yanhuo Zhang, Zhiyu Zhou, Bo Sheng, Zhuo Zhen, Xie Liu, Shouwen Diao, Mengwei Tu, Chen Qiu, Huixian Wang, Jianbo Zhang, Peng Zhu and Tong Li

Advanced Science, 2026
DOI: 10.1002/advs.202520748

Understanding the Photocatalytic Activity of Sodium Hexatitanate Nanoparticles for Pollutants Degradation: A Spectroscopic Insight

Ana Rita Ferreira Alves Teixeira, André Luiz Menezes de Oliveira, Florentina Neatu, Andrei Cristian Kuncser, Aurelian Catalin Galca, Arpad Mihai Rostas and Ieda Maria Garcia dos Santos

ACS Appl. Nano Mater., 2023, 6, 4477
DOI: 10.1021/acsanm.2c05577

Recent Advances in Metal–Organic Frameworks Derived Nanocomposites for Photocatalytic Applications in Energy and Environment

Mian Zahid Hussain, Zhuxian Yang, Zheng Huang, Quanli Jia, Yanqiu Zhu and Yongde Xia

Advanced Science, 2021, 8
DOI: 10.1002/advs.202100625

Metal-organic framework-derived multifunctional photocatalysts

Yaping Zhang, Jixiang Xu, Jie Zhou and Lei Wang

Chinese Journal of Catalysis, 2022, 43, 971
DOI: 10.1016/S1872-2067(21)63934-7