Gabriele Pupo, Francesco Ibba, David M. H. Ascough, Anna Chiara Vicini, Paolo Ricci, Kirsten E. Christensen, Lukas Pfeifer, John Richard Morphy, John M. Brown, Robert S. Paton and Véronique Gouverneur

Science, 2018, 360, 638
DOI: 10.1126/science.aar7941

Enantioselective Organocatalytic Fluorination‐Induced Wagner–Meerwein Rearrangement

Fedor Romanov‐Michailidis, Laure Guénée and Alexandre Alexakis

Angewandte Chemie, 2013, 125, 9436
DOI: 10.1002/ange.201303527

Enantioselective Organocatalytic Fluorination‐Induced Wagner–Meerwein Rearrangement

Fedor Romanov‐Michailidis, Laure Guénée and Alexandre Alexakis

Angew Chem Int Ed, 2013, 52, 9266
DOI: 10.1002/anie.201303527

A Base‐Free Neutral Phase‐Transfer Reaction System

Seiji Shirakawa, Lijia Wang, Rongjun He, Satoru Arimitsu and Keiji Maruoka

Chemistry An Asian Journal, 2014, 9, 1586
DOI: 10.1002/asia.201402194

Design of Chiral Bifunctional Quaternary Phosphonium Bromide Catalysts Possessing an Amide Moiety

Seiji Shirakawa, Takashi Tokuda, Atsuyuki Kasai and Keiji Maruoka

Org. Lett., 2013, 15, 3350
DOI: 10.1021/ol4013926

Effect of Brønsted acid co-catalyst in asymmetric conjugate addition of 3-aryloxindoles to maleimide under base-free phase-transfer conditions

Seiji Shirakawa, Hiroki Makino, Tomofumi Yoshidome and Keiji Maruoka

Tetrahedron, 2014, 70, 7128
DOI: 10.1016/j.tet.2014.06.017

Asymmetric Fluorination Reactions promoted by Chiral Hydrogen Bonding‐based Organocatalysts

Fernando Auria‐Luna, Somayeh Mohammadi, Masoumeh Divar, M. Concepción Gimeno and Raquel P. Herrera

Adv Synth Catal, 2020, 362, 5275
DOI: 10.1002/adsc.202000848

Designing Fluorinated Cinchona Alkaloids for Enantioselective Catalysis: Controlling Internal Rotation by a Fluorine‐Ammonium Ion gauche Effect (φNCCF)

Eva‐Maria Tanzer, W. Bernd Schweizer, Marc‐Olivier Ebert and Ryan Gilmour

Chemistry A European J, 2012, 18, 2006
DOI: 10.1002/chem.201102859

Chiral N‐Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination

Chuan‐Le Zhu, Mayaka Maeno, Fa‐Guang Zhang, Taiki Shigehiro, Takumi Kagawa, Kosuke Kawada, Norio Shibata, Jun‐An Ma and Dominique Cahard

Eur J Org Chem, 2013, 2013, 6501
DOI: 10.1002/ejoc.201300956

Enantioselective Synthesis of β,γ‐Unsaturated α‐Fluoroesters Catalyzed by N‐Heterocyclic Carbenes

Yu‐Ming Zhao, Man Sing Cheung, Zhenyang Lin and Jianwei Sun

Angew Chem Int Ed, 2012, 51, 10359
DOI: 10.1002/anie.201204521

P-Spiro phosphonium salts catalyzed asymmetric fluorination of 3-substituted benzofuran-2(3H)-ones

Chuan-Le Zhu, Xiao-Yun Fu, Ai-Jia Wei, Dominique Cahard and Jun-An Ma

Journal of Fluorine Chemistry, 2013, 150, 60
DOI: 10.1016/j.jfluchem.2013.03.007

The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki–Hiyama–Kishi Reaction

Qing‐Hai Deng, Hubert Wadepohl and Lutz H. Gade

Chemistry A European J, 2011, 17, 14922
DOI: 10.1002/chem.201102375

Catalytic Strategies for the Asymmetric Construction of Cyclic Frameworks with a Halogenated Tetrasubstituted Stereocenter

Yue Liu, Hai‐Jun Leng, Qing‐Zhu Li and Jun‐Long Li

Adv Synth Catal, 2020, 362, 3926
DOI: 10.1002/adsc.202000540

Rate acceleration of Diels–Alder reactions utilizing a fluorous micellar system in water

Kohsuke Nishimoto, Yohei Okada, Shokaku Kim and Kazuhiro Chiba

Electrochimica Acta, 2011, 56, 10626
DOI: 10.1016/j.electacta.2011.02.087

Enantioselective Organocatalytic Synthesis of Fluorinated Molecules

Guillem Valero, Xavier Companyó and Ramon Rios

Chemistry A European J, 2011, 17, 2018
DOI: 10.1002/chem.201001546

SPANamine derivatives in the catalytic asymmetric α-fluorination of β-keto esters

Olivier Jacquet, Nicolas D. Clément, Zoraida Freixa, Aurora Ruiz, Carmen Claver and Piet W.N.M. van Leeuwen

Tetrahedron: Asymmetry, 2011, 22, 1490
DOI: 10.1016/j.tetasy.2011.08.023

Stereoselective α-Chlorination of β-Keto Esters in the Presence of Hybrid Amide-Based Cinchona Alkaloids as Catalysts

Maciej Majdecki, Piotr Grodek and Janusz Jurczak

J. Org. Chem., 2021, 86, 995
DOI: 10.1021/acs.joc.0c02486

Chiral phase-transfer catalysis in the asymmetric α-heterofunctionalization of prochiral nucleophiles

Johannes Schörgenhumer, Maximilian Tiffner and Mario Waser

Beilstein J. Org. Chem., 2017, 13, 1753
DOI: 10.3762/bjoc.13.170

Modern Approaches for Asymmetric Construction of Carbon–Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs

Yi Zhu, Jianlin Han, Jiandong Wang, Norio Shibata, Mikiko Sodeoka, Vadim A. Soloshonok, Jaime A. S. Coelho and F. Dean Toste

Chem. Rev., 2018, 118, 3887
DOI: 10.1021/acs.chemrev.7b00778

ChemInform Abstract: Chiral Bifunctional Phase Transfer Catalysts for Asymmetric Fluorination of β‐Keto Esters.

Xisheng Wang, Quan Lan, Seiji Shirakawa and Keiji Maruoka

ChemInform, 2010, 41
DOI: 10.1002/chin.201019035

Catalytic Asymmetric Mono‐Fluorination of α‐Keto Esters: Synthesis of Optically Active β‐Fluoro‐α‐Hydroxy and β‐Fluoro‐α‐Amino Acid Derivatives

Shoko Suzuki, Yuki Kitamura, Sylvain Lectard, Yoshitaka Hamashima and Mikiko Sodeoka

Angew Chem Int Ed, 2012, 51, 4581
DOI: 10.1002/anie.201201303

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

Vivek Rauniyar, Aaron D. Lackner, Gregory L. Hamilton and F. Dean Toste

Science, 2011, 334, 1681
DOI: 10.1126/science.1213918

Gold‐Catalyzed Fluorination–Hydration: Synthesis of α‐Fluorobenzofuranones from 2‐Alkynylphenol Derivatives

Qiang Wang, Yu Jiang, Run Sun, Xiang‐Ying Tang and Min Shi

Chemistry A European J, 2016, 22, 14739
DOI: 10.1002/chem.201602545

Contemporary synthetic strategies in organofluorine chemistry

Robert Britton, Veronique Gouverneur, Jin-Hong Lin, Michael Meanwell, Chuanfa Ni, Gabriele Pupo, Ji-Chang Xiao and Jinbo Hu

Nat Rev Methods Primers, 2021, 1
DOI: 10.1038/s43586-021-00042-1

Hypervalent Iodine(III) Reagents with Transferable Primary Amines: Structure and Reactivity on the Electrophilic α-Amination of Stabilized Enolates

Diogo L. Poeira, Ana Cláudia R. Negrão, Hélio Faustino, Jaime A. S. Coelho, Clara S. B. Gomes, Pedro M. P. Gois and M. Manuel B. Marques

Org. Lett., 2022, 24, 776
DOI: 10.1021/acs.orglett.1c04312

Diastereoselective α-Fluorination of N-tert-Butanesulfinyl Imidates

Wei Huang, Yun Yao, Yan-Jun Xu and Chong-Dao Lu

J. Org. Chem., 2018, 83, 14777
DOI: 10.1021/acs.joc.8b02375

Asymmetric Preparation of α-Quaternary Fluorinated β-keto Esters. Review

Albert Granados and Adelina Vallribera

Molecules, 2020, 25, 3264
DOI: 10.3390/molecules25143264

Neue Entwicklungen bei asymmetrischen Phasentransferreaktionen

Seiji Shirakawa and Keiji Maruoka

Angewandte Chemie, 2013, 125, 4408
DOI: 10.1002/ange.201206835

Structural Study‐Guided Development of Versatile Phase‐Transfer Catalysts for Asymmetric Conjugate Additions of Cyanide

Brian A. Provencher, Keith J. Bartelson, Yan Liu, Bruce M. Foxman and Li Deng

Angew Chem Int Ed, 2011, 50, 10565
DOI: 10.1002/anie.201105536

Ion Pair Catalyst ‐ Pentanidinium

Yimin Qin, Zhenqiang Zhang, Xinyi Ye and Choon‐Hong Tan

The Chemical Record, 2023, 23
DOI: 10.1002/tcr.202200304

Improved Access to Chiral Tetranaphthoazepinium-Based Organocatalysts Using Aqueous Ammonia as Nitrogen Source

Auraya Manaprasertsak, Sorachat Tharamak, Christina Schedl, Alexander Roller and Michael Widhalm

Molecules, 2019, 24, 3844
DOI: 10.3390/molecules24213844

Enantioselective Cobalt-Catalyzed Sequential Nazarov Cyclization/Electrophilic Fluorination: Access to Chiral α-Fluorocyclopentenones

Heyi Zhang, Biao Cheng and Zhan Lu

Org. Lett., 2018, 20, 4028
DOI: 10.1021/acs.orglett.8b01597

Asymmetric Methods for Carbon‐Fluorine Bond Formation

Attila M. Remete, Melinda Nonn, Jorge Escorihuela, Santos Fustero and Loránd Kiss

Eur J Org Chem, 2021, 2021, 5946
DOI: 10.1002/ejoc.202101094

Pentanidium-Catalyzed Enantioselective Phase-Transfer Conjugate Addition Reactions

Ting Ma, Xiao Fu, Choon Wee Kee, Lili Zong, Yuanhang Pan, Kuo-Wei Huang and Choon-Hong Tan

J. Am. Chem. Soc., 2011, 133, 2828
DOI: 10.1021/ja1098353

Enantioselective halogenation via asymmetric phase‐transfer catalysis

Sunggi Lee and Won‐jin Chung

Bulletin Korean Chem Soc, 2022, 43, 896
DOI: 10.1002/bkcs.12546

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

Xiaoyu Yang, Tao Wu, Robert J. Phipps and F. Dean Toste

Chem. Rev., 2015, 115, 826
DOI: 10.1021/cr500277b

Enantioselective Fluorination of β-Ketoesters Catalyzed by Chiral Sodium Phosphate: Remarkable Enhancement of Reactivity by Simultaneous Utilization of Metal Enolate and Metal Phosphate

Keiji Mori, Ayaka Miyake and Takahiko Akiyama

Chemistry Letters, 2014, 43, 137
DOI: 10.1246/cl.130934

Comparative studies on the enantioselective fluorination of oxindoles with structurally modified N-fluorobenzenesulfonimides

Yan Zhang, Xian-Jin Yang, Tian Xie, Guan-Long Chen, Wen-Hua Zhu, Xiao-Qi Zhang, Xue-Yan Yang, Xin-Yan Wu, Xiao-Peng He and Hao-Ming He

Tetrahedron, 2013, 69, 4933
DOI: 10.1016/j.tet.2013.04.037

Diastereo- and Enantioselective Propargylation of Benzofuranones Catalyzed by Pybox-Copper Complex

Long Zhao, Guanxin Huang, Beibei Guo, Lijun Xu, Jie Chen, Weiguo Cao, Gang Zhao and Xiaoyu Wu

Org. Lett., 2014, 16, 5584
DOI: 10.1021/ol502615y

Asymmetric Neutral Amination of Nitroolefins Catalyzed by Chiral Bifunctional Ammonium Salts in Water‐Rich Biphasic Solvent

Lijia Wang, Seiji Shirakawa and Keiji Maruoka

Angewandte Chemie, 2011, 123, 5439
DOI: 10.1002/ange.201101307

Highly Enantioselective Fluorination of Unprotected 3-Substituted Oxindoles: One-Step Synthesis of BMS 204352 (MaxiPost)

Jun Li, Yunfei Cai, Weiliang Chen, Xiaohua Liu, Lili Lin and Xiaoming Feng

J. Org. Chem., 2012, 77, 9148
DOI: 10.1021/jo301705t

Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β‐Fluoroketones

Zhi‐Min Chen, Bin‐Miao Yang, Zhi‐Hua Chen, Qing‐Wei Zhang, Min Wang and Yong‐Qiang Tu

Chemistry A European J, 2012, 18, 12950
DOI: 10.1002/chem.201202444

Thiourea‐Catalyzed Enantioselective Fluorination of β‐Keto Esters

Junxing Xu, Yulai Hu, Danfeng Huang, Ke‐Hu Wang, Changming Xu and Teng Niu

Adv Synth Catal, 2012, 354, 515
DOI: 10.1002/adsc.201100660

Asymmetric Neutral Amination of Nitroolefins Catalyzed by Chiral Bifunctional Ammonium Salts in Water‐Rich Biphasic Solvent

Lijia Wang, Seiji Shirakawa and Keiji Maruoka

Angew Chem Int Ed, 2011, 50, 5327
DOI: 10.1002/anie.201101307

Catalytic asymmetric conjugate addition of α-fluoro β-ketophosphonates to nitroalkenes in the presence of nickel complexes

Hyun Ji Sung, Joo Yang Mang and Dae Young Kim

Journal of Fluorine Chemistry, 2015, 178, 40
DOI: 10.1016/j.jfluchem.2015.04.021

The Design of Environmentally-Benign, High-Performance Organocatalysts for Asymmetric Catalysis

Ryu Sakamoto and Keiji Maruoka

J. Syn. Org. Chem., Jpn., 2017, 75, 1141
DOI: 10.5059/yukigoseikyokaishi.75.1141

Phase-Transfer-Catalyzed Asymmetric Conjugate Cyanation of Alkylidenemalonates with KCN in the Presence of a Brønsted Acid Additive

Yan Liu, Seiji Shirakawa and Keiji Maruoka

Org. Lett., 2013, 15, 1230
DOI: 10.1021/ol400143m

Michael reaction in organocascade catalysis: A powerful tool for creating architectural complexity in the construction of medicinally privileged heterocyclic scaffolds

Ram Naresh Yadav, Md. Firoj Hossain, Devalina Ray, Ashok Kumar Srivastava and Bimal Krishna Banik

Catalysis Reviews, 2025, 67, 579
DOI: 10.1080/01614940.2024.2320802

An In Situ Directing Group Strategy for Chiral Anion Phase-Transfer Fluorination of Allylic Alcohols

Weiwei Zi, Yi-Ming Wang and F. Dean Toste

J. Am. Chem. Soc., 2014, 136, 12864
DOI: 10.1021/ja507468u

Enantioselective fluorination of α-chloro-β-keto phosphonates in the presence of chiral palladium complexes

Saet Byeol Woo, Chang Won Suh, Kwang Oh Koh and Dae Young Kim

Tetrahedron Letters, 2013, 54, 3359
DOI: 10.1016/j.tetlet.2013.04.054

Asymmetric phase-transfer reactions under base-free neutral conditions

Seiji Shirakawa and Keiji Maruoka

Tetrahedron Letters, 2014, 55, 3833
DOI: 10.1016/j.tetlet.2014.05.014

Enantioselective fluorination of β-ketoesters using tartrate derived bidentate bioxazoline-Cu(II) complexes

Kaluvu Balaraman, Ravichandran Vasanthan and Venkitasamy Kesavan

Tetrahedron: Asymmetry, 2013, 24, 919
DOI: 10.1016/j.tetasy.2013.07.004

Catalytic Asymmetric Mono‐Fluorination of α‐Keto Esters: Synthesis of Optically Active β‐Fluoro‐α‐Hydroxy and β‐Fluoro‐α‐Amino Acid Derivatives

Shoko Suzuki, Yuki Kitamura, Sylvain Lectard, Yoshitaka Hamashima and Mikiko Sodeoka

Angewandte Chemie, 2012, 124, 4659
DOI: 10.1002/ange.201201303

Phosphonium Salts in Asymmetric Catalysis: A Journey in a Decade's Extensive Research Work

Ajij Golandaj, Akil Ahmad and Deresh Ramjugernath

Adv Synth Catal, 2017, 359, 3676
DOI: 10.1002/adsc.201700795

Azaphosphatrane Cations: Weak Acids, Robust Phase‐transfer Catalysts

Pascal Dimitrov‐Raytchev, Jean‐Pierre Dutasta and Alexandre Martinez

ChemCatChem, 2012, 4, 2045
DOI: 10.1002/cctc.201200367

Asymmetric Total Synthesis of (−)‐Maoecrystal V

Wei‐bin Zhang, Wen‐bin Shao, Fu‐zhuo Li, Jian‐xian Gong and Zhen Yang

Chemistry An Asian Journal, 2015, 10, 1874
DOI: 10.1002/asia.201500564

N-Fluoro-(3,5-di-tert-butyl-4-methoxy)benzenesulfonimide (NFBSI): A sterically demanding electrophilic fluorinating reagent for enantioselective fluorination

Hiroyuki Yasui, Takeshi Yamamoto, Takehisa Ishimaru, Takeo Fukuzumi, Etsuko Tokunaga, Kakehi Akikazu, Motoo Shiro and Norio Shibata

Journal of Fluorine Chemistry, 2011, 132, 222
DOI: 10.1016/j.jfluchem.2011.01.005

Hydrogen Bonding Phase-Transfer Catalysis with Ionic Reactants: Enantioselective Synthesis of γ-Fluoroamines

Giulia Roagna, David M. H. Ascough, Francesco Ibba, Anna Chiara Vicini, Alberto Fontana, Kirsten E. Christensen, Aldo Peschiulli, Daniel Oehlrich, Antonio Misale, Andrés A. Trabanco, Robert S. Paton, Gabriele Pupo and Véronique Gouverneur

J. Am. Chem. Soc., 2020, 142, 14045
DOI: 10.1021/jacs.0c05131

Enantioselective Organocatalyzed Transformations of β-Ketoesters

Thavendran Govender, Per I. Arvidsson, Glenn E. M. Maguire, Hendrik G. Kruger and Tricia Naicker

Chem. Rev., 2016, 116, 9375
DOI: 10.1021/acs.chemrev.6b00156

Structural Study‐Guided Development of Versatile Phase‐Transfer Catalysts for Asymmetric Conjugate Additions of Cyanide

Brian A. Provencher, Keith J. Bartelson, Yan Liu, Bruce M. Foxman and Li Deng

Angewandte Chemie, 2011, 123, 10753
DOI: 10.1002/ange.201105536

Enantioselective Fluorination of α-Branched β-Ynone Esters Using a Cinchona-Based Phase-Transfer Catalyst

Satoru Arimitsu, Satsuki Iwasa and Ryunosuke Arakaki

J. Org. Chem., 2020, 85, 12804
DOI: 10.1021/acs.joc.0c01997

Scalable Synthesis of (R,R)-N,N-Dibenzyl-2-fluorocyclohexan-1-amine with CsF under Hydrogen Bonding Phase-Transfer Catalysis

Anna Chiara Vicini, Diké-Michel Alozie, Philippe Courtes, Giulia Roagna, Catherine Aubert, Victor Certal, Youssef El-Ahmad, Sébastien Roy and Véronique Gouverneur

Org. Process Res. Dev., 2021, 25, 2730
DOI: 10.1021/acs.oprd.1c00312

Syntheses and Applications of (Thio)Urea‐Containing Chiral Quaternary Ammonium Salt Catalysts

Johanna Novacek and Mario Waser

Eur J Org Chem, 2014, 2014, 802
DOI: 10.1002/ejoc.201301594

Recent Advances in Catalytic Enantioselective Fluorination Reactions

Sylvain Lectard, Yoshitaka Hamashima and Mikiko Sodeoka

Adv Synth Catal, 2010, 352, 2708
DOI: 10.1002/adsc.201000624

Enantioselective Synthesis of β,γ‐Unsaturated α‐Fluoroesters Catalyzed by N‐Heterocyclic Carbenes

Yu‐Ming Zhao, Man Sing Cheung, Zhenyang Lin and Jianwei Sun

Angewandte Chemie, 2012, 124, 10505
DOI: 10.1002/ange.201204521