Issue 73, 2016

Ruthenium-catalyzed 1,2,3-triazole directed intermolecular C–H amidation of arenes with sulfonyl azides

Abstract

Synthesis of 2-(2H-1,2,3-triazole-2-yl)aniline derivatives from 2-aryl-1,2,3-triazoles and sulfonylazides through ruthenium-catalyzed intermolecular C–H amidation is achieved. This reaction provides an environmentally benign protocol for C–N bond formation, producing N2 gas as the sole byproduct. Yet a number of functionalities are well tolerated, obtaining the desired products in moderate to excellent yields.

Graphical abstract: Ruthenium-catalyzed 1,2,3-triazole directed intermolecular C–H amidation of arenes with sulfonyl azides

Supplementary files

Article information

Article type
Communication
Submitted
30 Mot 2016
Accepted
14 Upu 2016
First published
15 Upu 2016

RSC Adv., 2016,6, 68929-68933

Ruthenium-catalyzed 1,2,3-triazole directed intermolecular C–H amidation of arenes with sulfonyl azides

X. Wang, C. Zhang, J. Li, C. Jiang, F. Su, Z. Zhan, L. Hai, Z. Chen and Y. Wu, RSC Adv., 2016, 6, 68929 DOI: 10.1039/C6RA14020C

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