Issue 26, 2024

Disparate reactivity of a chiral iron(ii) tetracarbene complex with organic azides

Abstract

A chiral tetra-NHC iron(II) complex and its disparate reactivity with multiple organic azides is reported. Both aryl and alkyl azides react with the iron(II) complex yielding three distinct products: an iron(IV) imide, an iron(IV) tetrazene, and a surprising and unprecedented double imide insertion complex.

Graphical abstract: Disparate reactivity of a chiral iron(ii) tetracarbene complex with organic azides

Supplementary files

Article information

Article type
Communication
Submitted
14 Mot 2024
Accepted
28 Mot 2024
First published
12 Jan 2024

Dalton Trans., 2024,53, 10819-10823

Disparate reactivity of a chiral iron(II) tetracarbene complex with organic azides

J. J. Russell, J. F. DeJesus, B. A. Smith, P. Nalaoh, K. D. Vogiatzis and D. M. Jenkins, Dalton Trans., 2024, 53, 10819 DOI: 10.1039/D4DT01422G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements