Flexible fluorinated graphite foils with high contents of the (C2F)n phase for slow neutron reflectors

Abstract

In order to prepare self-standing and flexible slow neutron reflectors made of graphite fluoride (GF) with high contents of (C₂F)_n structural phase, graphite foils of different thicknesses were used as starting materials for gas (F₂)/solid fluorination. The maximal interlayer distance of GF was obtained with this phase thanks to the stacking sequence FCCF/FCCF; this is mandatory for the efficient reflection of slow neutrons. 71 and 77% of the (C₂F)_n phase were achieved for graphite foils with thicknesses of 1.0 and 0.1 mm, respectively. The interlayer distances were 8.6 Å as expected. The fluorination conditions (static mode, a long duration of 24 h, annealing in pure F₂ gas for 24 h, and temperatures in the 390–460 °C range) were adapted to large pieces of graphite foils (7 × 7 cm²) in order to both avoid exfoliation and achieve a homogeneous dispersion of fluorine atoms. This process was also efficient for thinner (0.01 mm thick) graphitized graphene oxide foil. 56% of the (C₂F)_n phase and an interlayer of 8.6 Å were achieved for this foil when fluorination was performed at 430 °C. Whatever the nature and the thickness of the foil, their flexibilities are maintained.