Issue 83, 2023

Hydroxyfluorooxoborate (NH4)[C(NH2)3][B3O3F4(OH)] for exploring the effects of cation substitution on structure and optical properties

Abstract

Cation substitution is a straightforward but effective technique for improving the structure and properties; however, controlling directed substitution still poses significant difficulties. Herein, a metal-free hydroxyfluorooxoborate (NH4)[C(NH2)3][B3O3F4(OH)] has been synthesized using the strategy of heterologous substitution based on the template of A2[B3O3F4(OH)]. Tunable structure and optical properties have been achieved via varied A-site cation substitution. The intrinsic mechanism for this tunability was established by crystallography and theoretical research.

Graphical abstract: Hydroxyfluorooxoborate (NH4)[C(NH2)3][B3O3F4(OH)] for exploring the effects of cation substitution on structure and optical properties

Supplementary files

Article information

Article type
Communication
Submitted
02 Leo 2023
Accepted
20 Leo 2023
First published
29 Leo 2023

Chem. Commun., 2023,59, 12435-12438

Hydroxyfluorooxoborate (NH4)[C(NH2)3][B3O3F4(OH)] for exploring the effects of cation substitution on structure and optical properties

Z. Chen, F. Li, Z. Yang, S. Pan and M. Mutailipu, Chem. Commun., 2023, 59, 12435 DOI: 10.1039/D3CC04346K

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