Issue 61, 2022

Configurational ligand isomerism in conjoined-cages

Abstract

Double-decker shaped conjoined-cages of Pd3L4 formulation are prepared via self-assembly of Pd(II) with a set of three regioisomeric tridentate ligands. Alongside the targeted double-decker cage, unprecedented hour-glass shaped conjoined-cages of Pd3L4 formulation are also formed in two cases. The double-decker cage prepared from one ligand system and the hour-glass from another (but with a regioisomeric ligand) are structurally well suited to exemplify configurational ligand isomerism.

Graphical abstract: Configurational ligand isomerism in conjoined-cages

Supplementary files

Article information

Article type
Communication
Submitted
18 Mot 2022
Accepted
28 Jan 2022
First published
29 Jan 2022

Chem. Commun., 2022,58, 8480-8483

Configurational ligand isomerism in conjoined-cages

H. Dasary, M. Sarkar and D. K. Chand, Chem. Commun., 2022, 58, 8480 DOI: 10.1039/D2CC02837A

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