Issue 15, 2021
From the journal:

Journal of Materials Chemistry C

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers†

Yu Gong,‡a   Wang-Kang Han,‡a   Hui-Shu Lu,a   Qing-Tao Hu,a   Huan Tu,a   Pei-Ni Li,a   Xiaodong Yan ORCID logo a  and  Zhi-Guo Gu ORCID logo *ab  

* Corresponding authors

a The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P. R. China
E-mail: zhiguogu@jiangnan.edu.cn

b International Joint Research Center for Photoresponsive Molecules and Materials, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, P. R. China

Abstract

A ligand exchange induced single crystal to single crystal (SCSC) transformation from 3D Hofmann-type frameworks [Fe(ep)M(CN)4] (ep = ethylpyrazine; M = Pt, Pd) to 2D layer networks [Fe(mp)2M(CN)4] (mp = methoxypyrazine) was observed. Interestingly, the different pillar–ligands showed a significant influence on the structural assembly and spin-crossover properties.

Graphical abstract: Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

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Supplementary files

Article information

DOI
https://doi.org/10.1039/D1TC00470K
Article type
Communication
Submitted
30 Phe 2021
Accepted
18 Ube 2021
First published
19 Ube 2021

J. Mater. Chem. C, 2021,9, 5082-5087

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Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Y. Gong, W. Han, H. Lu, Q. Hu, H. Tu, P. Li, X. Yan and Z. Gu, J. Mater. Chem. C, 2021, 9, 5082 DOI: 10.1039/D1TC00470K

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