Issue 28, 2019
From the journal:

Dalton Transactions

NHC-stabilized silyl-substituted silyliumylidene ions†

Philipp Frischa  and  Shigeyoshi Inoue ORCID logo *a  

* Corresponding authors

a Department of Chemistry, WACKER-Institute of Silicon Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergtraße 4, 85748 Garching bei München, Germany
E-mail: s.inoue@tum.de

Abstract

The first silyl-substituted silyliumylidene ions are reported. The scope of a previously described convenient one-step procedure for the preparation of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions via dehydrochlorination from a Si(IV) precursor with NHCs is expanded to silyl-based substituents as well as aryl substituents with reduced steric bulk.

Graphical abstract: NHC-stabilized silyl-substituted silyliumylidene ions

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Article information

DOI
https://doi.org/10.1039/C9DT02010A
Article type
Communication
Submitted
14 Mot 2019
Accepted
18 Jan 2019
First published
19 Jan 2019

Dalton Trans., 2019,48, 10403-10406

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NHC-stabilized silyl-substituted silyliumylidene ions

P. Frisch and S. Inoue, Dalton Trans., 2019, 48, 10403 DOI: 10.1039/C9DT02010A

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