Issue 53, 2017

cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis

Abstract

Development of catalyst-controlled C–H hydroxylation could provide direct access to valuable synthetic targets, such as primary metabolites. Here, we report a new family of porous materials, comprised of 2-dimensional metalloporphyrin layers and flexible aliphatic linkers, and demonstrate C–H hydroxylation activity. We demonstrate that the stereochemistry of cis-decalin oxidation provides a useful tool for differentiating catalysis in from catalysis on porous materials, which is critical to leveraging the potential of porous materials for catalyst-controlled oxidation chemistry.

Graphical abstract: cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis

Supplementary files

Article information

Article type
Communication
Submitted
04 Mme 2017
Accepted
07 Jan 2017
First published
07 Jan 2017

Chem. Commun., 2017,53, 7377-7380

cis-Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis

A. D. Cardenal, H. Jeong Park, C. J. Chalker, K. G. Ortiz and D. C. Powers, Chem. Commun., 2017, 53, 7377 DOI: 10.1039/C7CC02570J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements