Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst

Hagit Ben-Daat; Christopher L. Rock; Marco Flores; Thomas L. Groy; Amanda C. Bowman; Ryan J. Trovitch

doi:10.1039/C7CC02281F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst†

Hagit Ben-Daat,^a Christopher L. Rock,^a Marco Flores,^a Thomas L. Groy,^a Amanda C. Bowman^b and Ryan J. Trovitch

*^a

Author affiliations

* Corresponding authors

^a School of Molecular Sciences, Arizona State University, Tempe, Arizona, USA
E-mail: ryan.trovitch@asu.edu
Tel: +1 480 727 8930

^b Department of Chemistry and Biochemistry, Colorado College, Colorado Springs, Colorado, USA

Abstract

Addition of NaEt₃BH to (^Ph2PPrDI)CoCl₂ affords the corresponding monohydride, (^Ph2PPrDI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(II) centre. Notably, (^Ph2PPrDI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions.

This article is part of the themed collection: 2017 Emerging Investigators

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C7CC02281F
Article type: Communication
Submitted: 25 Ube 2017
Accepted: 05 Mot 2017
First published: 05 Mot 2017

Download Citation

Chem. Commun., 2017,53, 7333-7336

Permissions

Request permissions

Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst

H. Ben-Daat, C. L. Rock, M. Flores, T. L. Groy, A. C. Bowman and R. J. Trovitch, Chem. Commun., 2017, 53, 7333 DOI: 10.1039/C7CC02281F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst

Social activity

Search articles by author

Spotlight

Advertisements