Issue 53, 2017
From the journal:

Chemical Communications

High molecular weight poly(N-methyl-B-vinylazaborine) – a semi-inorganic B–N polystyrene analogue†

Birk Thiedemann,abc   Philipp J. Gliese,abc   Jonas Hoffmann,c   Paul G. Lawrence,d   Frank D. Sönnichsen*c  and  Anne Staubitz ORCID logo *abc  

* Corresponding authors

a Institute for Organic and Analytical Chemistry, Leobener Str. NW2C, University of Bremen, 28359 Bremen, Germany
E-mail: staubitz@uni-bremen.de

b MAPEX Center for Materials and Processes, University of Bremen, Bibliothekstraße 1, 28359 Bremen, Germany

c Otto-Diels-Institute for Organic Chemistry, University of Kiel, Otto-Hahn-Platz 4, 24098 Kiel, Germany
E-mail: fsoennichsen@oc.uni-kiel.de

d School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK

Abstract

We present the synthesis of a B–N analogue of polystyrene, poly(N-methyl-B-vinylazaborine) in high molecular weight (MW = 24.9 kDa). Furthermore, it was possible to prepare a copolymer with the C–C analogue. A thorough comparison between the polymers by NMR spectroscopy, TGA, DSC and GPC showed significant differences between these polymers.

Graphical abstract: High molecular weight poly(N-methyl-B-vinylazaborine) – a semi-inorganic B–N polystyrene analogue

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Article information

DOI
https://doi.org/10.1039/C6CC08599G
Article type
Communication
Submitted
25 Mph 2016
Accepted
22 Tsh 2016
First published
22 Tsh 2016

Chem. Commun., 2017,53, 7258-7261

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High molecular weight poly(N-methyl-B-vinylazaborine) – a semi-inorganic B–N polystyrene analogue

B. Thiedemann, P. J. Gliese, J. Hoffmann, P. G. Lawrence, F. D. Sönnichsen and A. Staubitz, Chem. Commun., 2017, 53, 7258 DOI: 10.1039/C6CC08599G

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