Issue 62, 2016

Amine synthesis via transition metal homogeneous catalysed hydrosilylation

Abstract

Amines are among the most important compounds due to their wide applications in several areas of importance. Among the numerous synthetic methodologies, this review provides a comprehensive summary of the preparation of amines involving homogeneous transition metal catalysed hydrosilylation methodologies including the reduction of imine, amide, nitro and nitrile derivatives. In addition, challenging tandem reactions such as reductive amination or the use of CO2 as a C1-building block in N-methylation of amines will also be discussed.

Graphical abstract: Amine synthesis via transition metal homogeneous catalysed hydrosilylation

Article information

Article type
Review Article
Submitted
22 Mme 2016
Accepted
27 Mot 2016
First published
01 Jan 2016

RSC Adv., 2016,6, 57603-57625

Amine synthesis via transition metal homogeneous catalysed hydrosilylation

B. Li, J. Sortais and C. Darcel, RSC Adv., 2016, 6, 57603 DOI: 10.1039/C6RA10494K

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