Issue 16, 2016

Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

Abstract

A palladium-catalyzed construction for N-arylsulfonamide from nitroarenes and arylsulfonyl hydrazides is developed. In this protocol, abundant and stable nitroarenes serve as the nitrogen sources by in situ reduction reaction of hydrogen released from arylsulfonyl hydrazides. No external oxidants or reductants are needed for this kind of transformation.

Graphical abstract: Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

Supplementary files

Article information

Article type
Communication
Submitted
13 Tsh 2015
Accepted
21 Phe 2016
First published
26 Phe 2016

RSC Adv., 2016,6, 13010-13013

Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

F. Zhao, B. Li, H. Huang and G. Deng, RSC Adv., 2016, 6, 13010 DOI: 10.1039/C5RA26588F

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