Issue 38, 2016

Mechanical path to a photogenerated structure: ball milling-induced phase transition of a gold(i) complex

Abstract

Ball milling of blue-emitting crystal 1B of gold(I) isocyanide complex 1 induces a phase transition to yellow-emitting powder 1YG, which has the same solid structure as the previously reported 1Y obtained upon photoirradiation of 1B. This is the first example of mechanical stimulation inducing a phase change to a photo-accessible crystalline phase.

Graphical abstract: Mechanical path to a photogenerated structure: ball milling-induced phase transition of a gold(i) complex

Supplementary files

Article information

Article type
Communication
Submitted
28 Tsh 2015
Accepted
02 Kol 2016
First published
02 Kol 2016

CrystEngComm, 2016,18, 7217-7220

Mechanical path to a photogenerated structure: ball milling-induced phase transition of a gold(I) complex

K. Sakurada, T. Seki and H. Ito, CrystEngComm, 2016, 18, 7217 DOI: 10.1039/C5CE02565F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements