Issue 32, 2016

Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

Abstract

Chiral halogen bonding (S)-BINOL-based receptors are demonstrated to enhance the enantioselective recognition and sensing of chiral anions compared to their hydrogen bonding analogues. Computational studies attribute this behaviour to the strict linearity of halogen bonding (XB) and steric environment conferred by the XB donor groups bridged by the (S)-BINOL motif.

Graphical abstract: Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

Supplementary files

Article information

Article type
Communication
Submitted
25 Kol 2016
Accepted
15 Ube 2016
First published
15 Ube 2016

Chem. Commun., 2016,52, 5527-5530

Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

J. Y. C. Lim, I. Marques, L. Ferreira, V. Félix and P. D. Beer, Chem. Commun., 2016, 52, 5527 DOI: 10.1039/C6CC01701K

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