Issue 11, 2015

Direct borylation of benzyl alcohol and its analogues in the absence of bases

Abstract

Direct borylation of arylmethanols to synthesize important and useful benzylboronates was carried out through Pd(OAc)2-catalyzed sp3 C–O activation. This borylation is compatible with various functional groups under mild conditions in the absence of any bases, offering an atom- and step-economical way to produce benzylboron compounds.

Graphical abstract: Direct borylation of benzyl alcohol and its analogues in the absence of bases

Supplementary files

Article information

Article type
Research Article
Submitted
02 Pha 2015
Accepted
02 Leo 2015
First published
10 Leo 2015

Org. Chem. Front., 2015,2, 1505-1510

Author version available

Direct borylation of benzyl alcohol and its analogues in the absence of bases

Z. Cao, F. Luo, W. Shi and Z. Shi, Org. Chem. Front., 2015, 2, 1505 DOI: 10.1039/C5QO00243E

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