Issue 8, 2015

Palladium-catalyzed direct ortho C–O bond construction of azoxybenzenes with carboxylic acids and alcohols

Abstract

A Pd(II) catalyzed C–O bond formation of azoxybenzenes has been developed. An N-atom served as a directing group, as confirmed by the single crystal X-ray diffraction analysis of the palladium complex. The products were obtained in moderate to excellent yields for 29 examples. This protocol features high regioselectivity, wide functional group tolerance and atom economy.

Graphical abstract: Palladium-catalyzed direct ortho C–O bond construction of azoxybenzenes with carboxylic acids and alcohols

Supplementary files

Article information

Article type
Research Article
Submitted
12 Mme 2015
Accepted
02 Jan 2015
First published
03 Jan 2015

Org. Chem. Front., 2015,2, 951-955

Author version available

Palladium-catalyzed direct ortho C–O bond construction of azoxybenzenes with carboxylic acids and alcohols

D. Zhang, X. Cui, F. Yang, Q. Zhang, Y. Zhu and Y. Wu, Org. Chem. Front., 2015, 2, 951 DOI: 10.1039/C5QO00120J

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