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Three new alkaline earth metal based MOFs have been synthesized by using 4,4′-sulfobisbenzoic acid (SBBA) and alkaline earth metal salts M(NO3)2, M = Ca, Sr, Ba. These MOFs exhibit interesting structural diversity, variable chemical stability as well as proton conductivity.

Graphical abstract: Alkali earth metal (Ca, Sr, Ba) based thermostable metal–organic frameworks (MOFs) for proton conduction

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