Issue 3, 2011
From the journal:

Chemical Science

A dual-functional tetrakis-imidazoliummacrocycle for supramolecular assembly†

Christopher J. Serpell,a   James Cookson,b   Amber L. Thompsona  and  Paul D. Beer*a  

* Corresponding authors

a Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford, United Kingdom
E-mail: paul.beer@chem.ox.ac.uk
Fax: +44 (0) 1865 272609
Tel: +44 (0) 1865 285142

b Johnson Matthey Technology Centre, Blount's Court, Sonning Common, Reading, UK
E-mail: cooksj@matthey.com
Fax: +44(0) 118 924 2338
Tel: +44 (0) 118 924 2061

Abstract

A new versatile tetrakis-imidazolium macrocycle for use in supramolecular applications is reported. It displays excellent affinities for π-electron rich neutral guests such as 1,5-dihydroxynaphthalene derivatives and TTF, providing opportunities for the construction of interlocked molecules, as well as exhibiting extensive and potent anion coordination chemistry.

Graphical abstract: A dual-functional tetrakis-imidazolium macrocycle for supramolecular assembly

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Article information

DOI
https://doi.org/10.1039/C0SC00511H
Article type
Edge Article
Submitted
07 Mph 2010
Accepted
25 Pun 2010
First published
17 Tsh 2010

Chem. Sci., 2011,2, 494-500

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A dual-functional tetrakis-imidazolium macrocycle for supramolecular assembly

C. J. Serpell, J. Cookson, A. L. Thompson and P. D. Beer, Chem. Sci., 2011, 2, 494 DOI: 10.1039/C0SC00511H

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