Issue 8, 2008

Univalent transition metal complexes of arenes stabilized by a bulky terphenylligand: differences in the stability of Cr(i), Mn(i) or Fe(i) complexes

Abstract

Two univalent transition metal complexes, (µ-η66-C7H8){MnAr*-3,5-Pri2}2 (1) and (η6-C6H6)FeAr*-3,5-Pri2 (2) (Ar*-3,5-Pri2 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2), that have η6 arene coordination were synthesized by reduction of the corresponding metal halides. The complexes are thermally stable in contrast to the corresponding Cr(I) complexes of benzene or toluene which decompose at room temperature.

Graphical abstract: Univalent transition metal complexes of arenes stabilized by a bulky terphenyl ligand: differences in the stability of Cr(i), Mn(i) or Fe(i) complexes

Supplementary files

Article information

Article type
Communication
Submitted
01 Mph 2007
Accepted
28 Pun 2007
First published
20 Tsh 2007

Chem. Commun., 2008, 1014-1016

Univalent transition metal complexes of arenes stabilized by a bulky terphenyl ligand: differences in the stability of Cr(I), Mn(I) or Fe(I) complexes

C. Ni, B. D. Ellis, J. C. Fettinger, G. J. Long and P. P. Power, Chem. Commun., 2008, 1014 DOI: 10.1039/B715027J

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