Issue 16, 2016
From the journal:

RSC Advances

Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes†

Feng Zhao,a   Bin Li,a   Huawen Huanga  and  Guo-Jun Deng*ab  

* Corresponding authors

a Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China
E-mail: gjdeng@xtu.edu.cn
Fax: +86-0731-5829-2251
Tel: +86-0731-5829-8601

b Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Abstract

A palladium-catalyzed construction for N-arylsulfonamide from nitroarenes and arylsulfonyl hydrazides is developed. In this protocol, abundant and stable nitroarenes serve as the nitrogen sources by in situ reduction reaction of hydrogen released from arylsulfonyl hydrazides. No external oxidants or reductants are needed for this kind of transformation.

Graphical abstract: Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

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Article information

DOI
https://doi.org/10.1039/C5RA26588F
Article type
Communication
Submitted
13 Tsh 2015
Accepted
21 Phe 2016
First published
26 Phe 2016

RSC Adv., 2016,6, 13010-13013

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Palladium-catalyzed N-arylsulfonamide formation from arylsulfonyl hydrazides and nitroarenes

F. Zhao, B. Li, H. Huang and G. Deng, RSC Adv., 2016, 6, 13010 DOI: 10.1039/C5RA26588F

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